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Thermodynamic Modeling of Phase Formation in the Co–O–C–H–He System Full article

Journal Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613
Output data Year: 2026, Volume: 71, Number: 7, Pages: 960–963 Pages count : 4 DOI: 10.1134/S0036023626601248
Tags chemical vapor deposition, cobalt-containing coatings, cobalt acetylacetonate, cobalt oxide
Authors Shestakov V.A. 1,2 , Kosinova M.L. 1
Affiliations
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
2 Novosibirsk State University of Architecture and Civil Engineering

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation 121031700321-3

Abstract: The decomposition of cobalt acetylacetonate in a mixture with oxygen was studied using a thermodynamic approach to construct chemical vapor deposition diagrams. The calculations were performed using the database and software of the Electronic Materials Properties Database. The process was assumed to proceed in a quasi-equilibrium regime on a chemically inert substrate in the reactor temperature range of 473– 1073 K at a pressure of 1.333 or 101325 Pa. Calculations indicate that MOCVD processes can produce films containing, depending on the conditions, cobalt and cobalt oxides CoO and Co3O4, as well as various complexes of these phases, including mixtures with carbon. The results of this study may be useful for producing cobalt-containing coatings.
Cite: Shestakov V.A. , Kosinova M.L.
Thermodynamic Modeling of Phase Formation in the Co–O–C–H–He System
Russian Journal of Inorganic Chemistry. 2026. V.71. N7. P.960–963. DOI: 10.1134/S0036023626601248 WOS Scopus OpenAlex
Dates:
Submitted: Mar 11, 2026
Accepted: Apr 15, 2026
Published print: Aug 31, 2026
Identifiers:
≡ Web of science: WOS:001864361700015
≡ Scopus: 2-s2.0-105048885517
≡ OpenAlex: W7204807771
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