Heterometallic Re/Mo and Re/W cubane-type cluster complexes | Sciact

Heterometallic Re/Mo and Re/W cubane-type cluster complexes Научная публикация

Журнал

Inorganic chemistry frontiers
ISSN: 2052-1553 , E-ISSN: 2052-1545

Вых. Данные

Год: 2022, Том: 9, Номер: 1, Страницы: 186-194 Страниц : 9 DOI: 10.1039/d1qi01230d

Авторы

Pronin Aleksei S. ¹ , Gayfulin Yakov M. ¹ , Sukhikh Taisiya S. ¹ , Lavrov Alexander N. ¹ , Yanshole Vadim V. ² , Mironov Yuri V. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, 3, Acad. Lavrentiev ave., Novosibirsk, Russian Federation
2	International Tomography Center SB RAS, 630090, 3A, Institutskaya str., Novosibirsk, Russian Federation

A series of heterometallic tetrahedral cluster complexes with the general formula [{MxRe4−xSe4}(CN)12]n− (M = Mo, W; x = 2, 3) were obtained using the reaction of ReI3 and MO3 with selenium and KCN at elevated temperatures. Compounds [ReW3Se4(CN)12]6− and [Re2W2Se4(CN)12]6− are the first rhenium–tungsten heterometallic clusters. Crystal structures, electrochemical properties in aqueous solutions and magnetic properties of crystalline samples have been studied in detail. It has been shown that new cluster anions demonstrate a regular change in geometric characteristics and redox potentials depending on the composition of the cluster core.

Pronin A.S. , Gayfulin Y.M. , Sukhikh T.S. , Lavrov A.N. , Yanshole V.V. , Mironov Y.V.
Heterometallic Re/Mo and Re/W cubane-type cluster complexes
Inorganic chemistry frontiers. 2022. V.9. N1. P.186-194. DOI: 10.1039/d1qi01230d WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:000722289900001
Scopus:	2-s2.0-85121838178
РИНЦ:	47548493
OpenAlex:	W3213085224

БД	Цитирований
Scopus	2
OpenAlex	2
РИНЦ	2