Heterometallic Re/Mo and Re/W cubane-type cluster complexes

Heterometallic Re/Mo and Re/W cubane-type cluster complexes Full article

Journal

Inorganic chemistry frontiers
ISSN: 2052-1553 , E-ISSN: 2052-1545

Output data

Year: 2022, Volume: 9, Number: 1, Pages: 186-194 Pages count : 9 DOI: 10.1039/d1qi01230d

Authors

Pronin Aleksei S. ¹ , Gayfulin Yakov M. ¹ , Sukhikh Taisiya S. ¹ , Lavrov Alexander N. ¹ , Yanshole Vadim V. ² , Mironov Yuri V. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, 3, Acad. Lavrentiev ave., Novosibirsk, Russian Federation
2	International Tomography Center SB RAS, 630090, 3A, Institutskaya str., Novosibirsk, Russian Federation

A series of heterometallic tetrahedral cluster complexes with the general formula [{MxRe4−xSe4}(CN)12]n− (M = Mo, W; x = 2, 3) were obtained using the reaction of ReI3 and MO3 with selenium and KCN at elevated temperatures. Compounds [ReW3Se4(CN)12]6− and [Re2W2Se4(CN)12]6− are the first rhenium–tungsten heterometallic clusters. Crystal structures, electrochemical properties in aqueous solutions and magnetic properties of crystalline samples have been studied in detail. It has been shown that new cluster anions demonstrate a regular change in geometric characteristics and redox potentials depending on the composition of the cluster core.

Pronin A.S. , Gayfulin Y.M. , Sukhikh T.S. , Lavrov A.N. , Yanshole V.V. , Mironov Y.V.
Heterometallic Re/Mo and Re/W cubane-type cluster complexes
Inorganic chemistry frontiers. 2022. V.9. N1. P.186-194. DOI: 10.1039/d1qi01230d WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:000722289900001
Scopus:	2-s2.0-85121838178
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