Effect of spin–phonon interactions on Urbach tails in flexible [M2(bdc)2(dabco)]

Effect of spin–phonon interactions on Urbach tails in flexible [M2(bdc)2(dabco)] Научная публикация

Журнал

PCCP: PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN: 1463-9084

Вых. Данные

Год: 2020, Том: 22, Номер: 27, Страницы: 15242-15247 Страниц : 6 DOI: 10.1039/d0cp01944e

Авторы

Kozlova Svetlana G. ¹ , Ryzhikov Maxim R. ¹ , Shayapov Vladimir R. ¹ , Samsonenko Denis G. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Academician Lavrentiev Avenue 3, Novosibirsk, Russian Federation

The optical properties of metal–organic frameworks [M2(bdc)2(dabco)] (M = Co, Ni, Cu, Zn) in the wavelength region of 300–1000 nm were studied, and the electronic band-to-band transitions were determined and characterized by the Kubelka–Munk approach and DFT calculations. Urbach edges for band-to-band transitions were determined. The effect of spin–phonon interactions on the width of Urbach edges in paramagnetic [M2(bdc)2(dabco)] is discussed. The obtained data may be useful to interpret polymerization, hybridization, and catalytic reactions in [M2(bdc)2(dabco)] pores and to design electronic and optical devices.

Kozlova S.G. , Ryzhikov M.R. , Shayapov V.R. , Samsonenko D.G.
Effect of spin–phonon interactions on Urbach tails in flexible [M2(bdc)2(dabco)]
PCCP: PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 2020. V.22. N27. P.15242-15247. DOI: 10.1039/d0cp01944e WOS Scopus OpenAlex

Поступила в редакцию:	10 апр. 2020 г.
Принята к публикации:	15 июн. 2020 г.
Опубликована online:	15 июн. 2020 г.

Web of science:	WOS:000549894000007
Scopus:	2-s2.0-85088262216
OpenAlex:	W3034618725

БД	Цитирований
OpenAlex	11
Scopus	7
Web of science	9