Effect of spin–phonon interactions on Urbach tails in flexible [M2(bdc)2(dabco)]

Effect of spin–phonon interactions on Urbach tails in flexible [M2(bdc)2(dabco)] Full article

Journal

PCCP: PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN: 1463-9084

Output data

Year: 2020, Volume: 22, Number: 27, Pages: 15242-15247 Pages count : 6 DOI: 10.1039/d0cp01944e

Authors

Kozlova Svetlana G. ¹ , Ryzhikov Maxim R. ¹ , Shayapov Vladimir R. ¹ , Samsonenko Denis G. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Academician Lavrentiev Avenue 3, Novosibirsk, Russian Federation

The optical properties of metal–organic frameworks [M2(bdc)2(dabco)] (M = Co, Ni, Cu, Zn) in the wavelength region of 300–1000 nm were studied, and the electronic band-to-band transitions were determined and characterized by the Kubelka–Munk approach and DFT calculations. Urbach edges for band-to-band transitions were determined. The effect of spin–phonon interactions on the width of Urbach edges in paramagnetic [M2(bdc)2(dabco)] is discussed. The obtained data may be useful to interpret polymerization, hybridization, and catalytic reactions in [M2(bdc)2(dabco)] pores and to design electronic and optical devices.

Kozlova S.G. , Ryzhikov M.R. , Shayapov V.R. , Samsonenko D.G.
Effect of spin–phonon interactions on Urbach tails in flexible [M2(bdc)2(dabco)]
PCCP: PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 2020. V.22. N27. P.15242-15247. DOI: 10.1039/d0cp01944e WOS Scopus OpenAlex

Submitted:	Apr 10, 2020
Accepted:	Jun 15, 2020
Published online:	Jun 15, 2020

Web of science:	WOS:000549894000007
Scopus:	2-s2.0-85088262216
OpenAlex:	W3034618725

DB	Citing
OpenAlex	10
Scopus	7
Web of science	8