Synthesis and structure of novel coordination compounds based on [Re6Q8(CN)6]4– (Q = S, Se) and (SnMe3)+

Synthesis and structure of novel coordination compounds based on [Re6Q8(CN)6]4– (Q = S, Se) and (SnMe3)+ Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2007, Volume: 33, Number: 12, Pages: 876-885 Pages count : 10 DOI: 10.1134/s1070328407120020

Tags

Coordination Chemistry. Equatorial Plane, Prussian Blue, Coordination Polyhedron, Cyano Group

Authors

Tarasenko M.S. ¹ , Ledneva A.Yu. ¹ , Kurat'eva N.V. ¹ , Naumov D.Yu. ¹ , Kim Sung Jin ² , Fedorov V.E. ¹ , Naumov N.G. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences , Novosibirsk, Russia
2	Department of Chemistry Ewha Womans University Seoul, Korea

The reactions of SnMe3Cl with salts of the cluster anionic complexes [Re6Q8(CN)6]4− (Q = S, Se) gave novel complexes [{(SnMe3)2(OH)}2{SnMe3}2{Re6S8(CN)6}] (I), (Me4N)2[{SnMe3(H2O)}2{Re6Se8(CN)6}] (II), [{(SnMe2)4(μ3-O)}2{Re6Se8(CN)6}] (III), and [(SnMe2)4(μ3-O)2(μ2-OH)2(H2O)2][{SnMe32{Re6Se8(CN)6}] (IV). The structures of I–IV were determined by X-ray diffraction. Compounds I, IV have the chain structures with the CN-SnMe3-NC bridges between the cluster anions [Re6Q8(CN)6]4−. Compound II contains isolated fragments {SnMe3(H2O)}2{Re6Se8(CN)6}2−. In the polymer framework of compound III, the cluster anionic complexes [Re6Se8(CN)6]4− are bound by the complex cations [(SnMe2)4(μ3-O)2]4+ formed due to the hydrolysis of the initial (SnMe3)Cl.

Tarasenko M.S. , Ledneva A.Y. , Kurat'eva N.V. , Naumov D.Y. , Kim S.J. , Fedorov V.E. , Naumov N.G.
Synthesis and structure of novel coordination compounds based on [Re6Q8(CN)6]4– (Q = S, Se) and (SnMe3)+
Russian Journal of Coordination Chemistry. 2007. V.33. N12. P.876-885. DOI: 10.1134/s1070328407120020 WOS Scopus OpenAlex

Submitted:	Nov 3, 2006
Accepted:	Nov 3, 2006
Published print:	Dec 1, 2007
Published online:	Dec 1, 2007

Web of science:	WOS:000251755300002
Scopus:	2-s2.0-37549001723
OpenAlex:	W1970116923

DB	Citing
OpenAlex	10
Scopus	9
Web of science	8