Synthesis and structure of novel coordination compounds based on [Re6Q8(CN)6]4– (Q = S, Se) and (SnMe3)+ Научная публикация
| Журнал |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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| Вых. Данные | Год: 2007, Том: 33, Номер: 12, Страницы: 876-885 Страниц : 10 DOI: 10.1134/s1070328407120020 | ||||
| Ключевые слова | Coordination Chemistry. Equatorial Plane, Prussian Blue, Coordination Polyhedron, Cyano Group | ||||
| Авторы |
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| Организации |
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Реферат:
The reactions of SnMe3Cl with salts of the cluster anionic complexes [Re6Q8(CN)6]4− (Q = S, Se) gave novel complexes [{(SnMe3)2(OH)}2{SnMe3}2{Re6S8(CN)6}] (I), (Me4N)2[{SnMe3(H2O)}2{Re6Se8(CN)6}] (II), [{(SnMe2)4(μ3-O)}2{Re6Se8(CN)6}] (III), and [(SnMe2)4(μ3-O)2(μ2-OH)2(H2O)2][{SnMe32{Re6Se8(CN)6}] (IV). The structures of I–IV were determined by X-ray diffraction. Compounds I, IV have the chain structures with the CN-SnMe3-NC bridges between the cluster anions [Re6Q8(CN)6]4−. Compound II contains isolated fragments {SnMe3(H2O)}2{Re6Se8(CN)6}2−. In the polymer framework of compound III, the cluster anionic complexes [Re6Se8(CN)6]4− are bound by the complex cations [(SnMe2)4(μ3-O)2]4+ formed due to the hydrolysis of the initial (SnMe3)Cl.
Библиографическая ссылка:
Tarasenko M.S.
, Ledneva A.Y.
, Kurat'eva N.V.
, Naumov D.Y.
, Kim S.J.
, Fedorov V.E.
, Naumov N.G.
Synthesis and structure of novel coordination compounds based on [Re6Q8(CN)6]4– (Q = S, Se) and (SnMe3)+
Russian Journal of Coordination Chemistry. 2007. V.33. N12. P.876-885. DOI: 10.1134/s1070328407120020 WOS Scopus OpenAlex
Synthesis and structure of novel coordination compounds based on [Re6Q8(CN)6]4– (Q = S, Se) and (SnMe3)+
Russian Journal of Coordination Chemistry. 2007. V.33. N12. P.876-885. DOI: 10.1134/s1070328407120020 WOS Scopus OpenAlex
Даты:
| Поступила в редакцию: | 3 нояб. 2006 г. |
| Принята к публикации: | 3 нояб. 2006 г. |
| Опубликована в печати: | 1 дек. 2007 г. |
| Опубликована online: | 1 дек. 2007 г. |
Идентификаторы БД:
| Web of science: | WOS:000251755300002 |
| Scopus: | 2-s2.0-37549001723 |
| OpenAlex: | W1970116923 |