Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu)

Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu) Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2009, Number: 19, Article number : 2655, Pages count : 3 DOI: 10.1039/b820722d

Authors

Tarasenko Maria S. ¹ , Golenkov Eugeny O. ¹ , Naumov Nikolay G. ¹ , Moroz Nikolay K. ¹ , Fedorov Vladimir E. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Acad. Lavrentieva ave., Novosibirsk, Russia

X-Ray studies and 1H NMR measurements for novel cyano-bridged polymers [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu) reveal temperature dependence of proton localization: acid protons are trapped between nitrogen atoms at low temperatures, but can be transferred to the water sublattice at higher temperatures; this transfer resulted in intermolecular proton exchange.

Tarasenko M.S. , Golenkov E.O. , Naumov N.G. , Moroz N.K. , Fedorov V.E.
Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu)
Chemical Communications. 2009. N19. 2655 :1-3. DOI: 10.1039/b820722d WOS Scopus OpenAlex

Submitted:	Nov 19, 2008
Accepted:	Feb 23, 2009
Published online:	Mar 20, 2009
Published print:	Mar 21, 2009

Web of science:	WOS:000265890600009
Scopus:	2-s2.0-65549128632
OpenAlex:	W1996422392

DB	Citing
OpenAlex	19
Scopus	21
Web of science	20