Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu) Научная публикация
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Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X |
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| Вых. Данные | Год: 2009, Номер: 19, Номер статьи : 2655, Страниц : 3 DOI: 10.1039/b820722d | ||
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Реферат:
X-Ray studies and 1H NMR measurements for novel cyano-bridged polymers [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu) reveal temperature dependence of proton localization: acid protons are trapped between nitrogen atoms at low temperatures, but can be transferred to the water sublattice at higher temperatures; this transfer resulted in intermolecular proton exchange.
Библиографическая ссылка:
Tarasenko M.S.
, Golenkov E.O.
, Naumov N.G.
, Moroz N.K.
, Fedorov V.E.
Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu)
Chemical Communications. 2009. N19. 2655 :1-3. DOI: 10.1039/b820722d WOS Scopus OpenAlex
Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu)
Chemical Communications. 2009. N19. 2655 :1-3. DOI: 10.1039/b820722d WOS Scopus OpenAlex
Даты:
| Поступила в редакцию: | 19 нояб. 2008 г. |
| Принята к публикации: | 23 февр. 2009 г. |
| Опубликована online: | 20 мар. 2009 г. |
| Опубликована в печати: | 21 мар. 2009 г. |
Идентификаторы БД:
| Web of science: | WOS:000265890600009 |
| Scopus: | 2-s2.0-65549128632 |
| OpenAlex: | W1996422392 |