Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu)

Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu) Научная публикация

Журнал

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Вых. Данные

Год: 2009, Номер: 19, Номер статьи : 2655, Страниц : 3 DOI: 10.1039/b820722d

Авторы

Tarasenko Maria S. ¹ , Golenkov Eugeny O. ¹ , Naumov Nikolay G. ¹ , Moroz Nikolay K. ¹ , Fedorov Vladimir E. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Acad. Lavrentieva ave., Novosibirsk, Russia

X-Ray studies and 1H NMR measurements for novel cyano-bridged polymers [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu) reveal temperature dependence of proton localization: acid protons are trapped between nitrogen atoms at low temperatures, but can be transferred to the water sublattice at higher temperatures; this transfer resulted in intermolecular proton exchange.

Tarasenko M.S. , Golenkov E.O. , Naumov N.G. , Moroz N.K. , Fedorov V.E.
Unusual H-bonding in novel cyano-cluster polymeric hydrates [(H){Ln(H2O)4}{Re6S8(CN)6}]·2H2O (Ln = Yb, Lu)
Chemical Communications. 2009. N19. 2655 :1-3. DOI: 10.1039/b820722d WOS Scopus OpenAlex

Поступила в редакцию:	19 нояб. 2008 г.
Принята к публикации:	23 февр. 2009 г.
Опубликована online:	20 мар. 2009 г.
Опубликована в печати:	21 мар. 2009 г.

Web of science:	WOS:000265890600009
Scopus:	2-s2.0-65549128632
OpenAlex:	W1996422392

БД	Цитирований
OpenAlex	20
Scopus	21
Web of science	20