Abstract: By the interaction of aqueous solutions of salts of the [Re6Se8(CN)6]4− cluster anion with salts of Nd(III), Tb(III), and Yb(III) lanthanides in the presence of tetraatomic alcohol erythritol (butane-1,2R,3S,4-tetraol) three new compounds are obtained: K[Nd(C4H10O4)(H2O)4{Re6Se8(CN)6}]·4H2O (P \( \bar 1 \) space group, a = 11.544 Å, b = 13.643 Å, c = 13.838 Å, α = 111.97°, β = 108.08°, γ = 90.08°) (1); [{Yb2(C4H9O4)2 × (H2O)2}{Re6Se8(CN)6}]·5H2O (P \( \bar 1 \) space group, a = 10.308 Å, b = 10.505 Å, c = 11.154 Å, α = 88.21°, β = 81.83°, γ = 78.50°) (2); [{Tb2(C4H9O4)2(C4H10O4)}{Re6Se8(CN)6}]·4H2O (P \( \bar 1 \) space group, a = 10.002 Å, b = 10.276 Å, c = 11.762 Å, α = 91.32°, β = 104.01°, γ = 106.02°) (3). The structures of these compounds are the coordination polymers (chain (2) and grids (1 and 3)) with different coordination modes of erythritol to the lanthanide cations.

Cite: Tarasenko M.S. , Ledneva A.Y. , Naumov D.Y. , Naumov N.G. , Fedorov V.E.
Coordination polymers based on [Re6Se8(CN)6]4− cluster anion, lanthanide cations, and tetraatomic alcohol erythritol
Journal of Structural Chemistry. 2011. V.52. N1. P.172-179. DOI: 10.1134/s0022476611010239 Scopus OpenAlex

Dates:

Submitted:	Feb 4, 2010
Accepted:	Mar 15, 2010
Published print:	Feb 28, 2011
Published online:	Mar 31, 2011

Identifiers:

Scopus:	2-s2.0-79960071637
OpenAlex:	W2035156950

Citing:

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