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Coordination polymers based on [Re6Se8(CN)6]4− cluster anion, lanthanide cations, and tetraatomic alcohol erythritol Научная публикация

Журнал Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766
Вых. Данные Год: 2011, Том: 52, Номер: 1, Страницы: 172-179 Страниц : 8 DOI: 10.1134/s0022476611010239
Ключевые слова rhenium, octahedral cluster, cyanide complex, lanthanides, synthesis, crystal structure, polyatomic alcohol
Авторы Tarasenko M.S. 1 , Ledneva A.Yu. 1 , Naumov D.Yu. 1 , Naumov N.G. 1 , Fedorov V.E. 1
Организации
1 A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

Реферат: By the interaction of aqueous solutions of salts of the [Re6Se8(CN)6]4− cluster anion with salts of Nd(III), Tb(III), and Yb(III) lanthanides in the presence of tetraatomic alcohol erythritol (butane-1,2R,3S,4-tetraol) three new compounds are obtained: K[Nd(C4H10O4)(H2O)4{Re6Se8(CN)6}]·4H2O (P \( \bar 1 \) space group, a = 11.544 Å, b = 13.643 Å, c = 13.838 Å, α = 111.97°, β = 108.08°, γ = 90.08°) (1); [{Yb2(C4H9O4)2 × (H2O)2}{Re6Se8(CN)6}]·5H2O (P \( \bar 1 \) space group, a = 10.308 Å, b = 10.505 Å, c = 11.154 Å, α = 88.21°, β = 81.83°, γ = 78.50°) (2); [{Tb2(C4H9O4)2(C4H10O4)}{Re6Se8(CN)6}]·4H2O (P \( \bar 1 \) space group, a = 10.002 Å, b = 10.276 Å, c = 11.762 Å, α = 91.32°, β = 104.01°, γ = 106.02°) (3). The structures of these compounds are the coordination polymers (chain (2) and grids (1 and 3)) with different coordination modes of erythritol to the lanthanide cations.
Библиографическая ссылка: Tarasenko M.S. , Ledneva A.Y. , Naumov D.Y. , Naumov N.G. , Fedorov V.E.
Coordination polymers based on [Re6Se8(CN)6]4− cluster anion, lanthanide cations, and tetraatomic alcohol erythritol
Journal of Structural Chemistry. 2011. V.52. N1. P.172-179. DOI: 10.1134/s0022476611010239 Scopus OpenAlex
Даты:
Поступила в редакцию: 4 февр. 2010 г.
Принята к публикации: 15 мар. 2010 г.
Опубликована в печати: 28 февр. 2011 г.
Опубликована online: 31 мар. 2011 г.
Идентификаторы БД:
Scopus: 2-s2.0-79960071637
OpenAlex: W2035156950
Цитирование в БД:
БД Цитирований
OpenAlex 11
Scopus 11
Альметрики: