Structure of coordination polymers Cs5[{Ln(H2O)4(C2H6O)}{Re6Se8(CN)6}2]·2H2O (Ln = La, Nd)

Structure of coordination polymers Cs5[{Ln(H2O)4(C2H6O)}{Re6Se8(CN)6}2]·2H2O (Ln = La, Nd) Научная публикация

Журнал

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Вых. Данные

Год: 2015, Том: 56, Номер: 6, Страницы: 1143-1147 Страниц : 5 DOI: 10.1134/s0022476615060189

Ключевые слова

rhenium, octahedral cluster, rare earth elements (REE), synthesis, complex compounds, crystal structure

Авторы

Tarasenko M.S. ¹ , Naumov N.G. ^1,2 , Kuratieva N.V. ^1,2

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk National Research State University, Novosibirsk, Russia

Two new Cs5[{Ln(H2O)4(C2H6O)}{Re6Se9(CN)6}2]·2H2O (Ln = La, Nd) compounds are obtained by the interaction of aqueous Cs3KRe6S8(CN)6 and LnCl3 solutions in the presence of ethanol. These compounds are isostructural, and crystallize in the tetragonal crystal system (space group P4/ncc) with the following unit cell parameters: a = 17.9102 Å, c = 19.6694 Å for La, and a = 17.8846 Å, c = 19.6425 Å for Nd. The structure of the compounds consists of corrugated [{Ln(H2O)4(C2H6O)}{Re6Se8(CN)6}2]5–layers. Cesium cations compensating the negative charge are located in both cavities of the corrugated layer and between the layers.

Tarasenko M.S. , Naumov N.G. , Kuratieva N.V.
Structure of coordination polymers Cs5[{Ln(H2O)4(C2H6O)}{Re6Se8(CN)6}2]·2H2O (Ln = La, Nd)
Journal of Structural Chemistry. 2015. V.56. N6. P.1143-1147. DOI: 10.1134/s0022476615060189 WOS Scopus OpenAlex

Поступила в редакцию:	27 июн. 2014 г.
Принята к публикации:	27 июн. 2014 г.
Опубликована в печати:	1 нояб. 2015 г.
Опубликована online:	23 янв. 2016 г.

Web of science:	WOS:000368734000018
Scopus:	2-s2.0-84955482063
OpenAlex:	W2344139242

БД	Цитирований
OpenAlex	4
Scopus	4
Web of science	3