Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2)

Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2) Full article

Journal

Journal of Molecular Structure
ISSN: 0022-2860 , E-ISSN: 1872-8014

Output data

Year: 2017, Volume: 1141, Pages: 115-118 Pages count : 4 DOI: 10.1016/j.molstruc.2017.03.093

Authors

Savkov Boris Yu. ¹ , Virovets Alexander V. ^1,2 , Maksakov Vladimir A. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences
2	Novosibirsk State University

Dichloroacetonitrile undergoes hydrogenation by triosmium dihydride cluster under mild conditions. The reaction of cluster complex (μ-H)2Os3(CO)10 (1) with CHCl2CN in the presence of morpholine as a base results in two novel compounds (μ-Cl)Os3(CO)10(μ-N=CHCHCl2) (2) and (μ-H)Os3(CO)10(μ,η2-HN=CHCHCl2) (3). Both compounds were characterized using FTIR, 13C, 1H NMR spectra, and CHN analysis, molecular structure of 2 was determined by X-Ray diffraction study.

Savkov B.Y. , Virovets A.V. , Maksakov V.A.
Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2)
Journal of Molecular Structure. 2017. V.1141. P.115-118. DOI: 10.1016/j.molstruc.2017.03.093 WOS Scopus РИНЦ OpenAlex

Submitted:	Dec 26, 2016
Accepted:	Mar 25, 2017
Published print:	Mar 25, 2017
Published online:	Mar 30, 2017

Web of science:	WOS:000401593400015
Scopus:	2-s2.0-85016311271
Elibrary:	29497521
OpenAlex:	W2597795327

DB	Citing
Web of science	2
Scopus	2
Elibrary	2
OpenAlex	2