Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2) Научная публикация
| Журнал |
Journal of Molecular Structure
ISSN: 0022-2860 , E-ISSN: 1872-8014 |
||||
|---|---|---|---|---|---|
| Вых. Данные | Год: 2017, Том: 1141, Страницы: 115-118 Страниц : 4 DOI: 10.1016/j.molstruc.2017.03.093 | ||||
| Авторы |
|
||||
| Организации |
|
Реферат:
Dichloroacetonitrile undergoes hydrogenation by triosmium dihydride cluster under mild conditions. The reaction of cluster complex (μ-H)2Os3(CO)10 (1) with CHCl2CN in the presence of morpholine as a base results in two novel compounds (μ-Cl)Os3(CO)10(μ-N=CHCHCl2) (2) and (μ-H)Os3(CO)10(μ,η2-HN=CHCHCl2) (3). Both compounds were characterized using FTIR, 13C, 1H NMR spectra, and CHN analysis, molecular structure of 2 was determined by X-Ray diffraction study.
Библиографическая ссылка:
Savkov B.Y.
, Virovets A.V.
, Maksakov V.A.
Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2)
Journal of Molecular Structure. 2017. V.1141. P.115-118. DOI: 10.1016/j.molstruc.2017.03.093 WOS Scopus РИНЦ OpenAlex
Dichloroacetonitrile hydrogenation by osmium cluster: Crystal structure of (μ-Cl)Os3(CO)10(μ-N=CHCHCl2)
Journal of Molecular Structure. 2017. V.1141. P.115-118. DOI: 10.1016/j.molstruc.2017.03.093 WOS Scopus РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 26 дек. 2016 г. |
| Принята к публикации: | 25 мар. 2017 г. |
| Опубликована в печати: | 25 мар. 2017 г. |
| Опубликована online: | 30 мар. 2017 г. |
Идентификаторы БД:
| Web of science: | WOS:000401593400015 |
| Scopus: | 2-s2.0-85016311271 |
| РИНЦ: | 29497521 |
| OpenAlex: | W2597795327 |