THE PREPARATION OF RHODIUM(III) NITRITE COMPLEXES WITH ETHYLENEDIAMINE

THE PREPARATION OF RHODIUM(III) NITRITE COMPLEXES WITH ETHYLENEDIAMINE Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2022, Volume: 63, Number: 4, Pages: 569-579 Pages count : 11 DOI: 10.1134/S0022476622040072

Tags

complexes, rhodium, ethylenediamine, nitrites, crystal structure.

Authors

Vorobyeva S.N. ¹ , Baidina I.A. ¹ , Sukhikh T.S. ¹ , Korolkov I.V. ^1,2 , Belyaev A.V. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
2	Kemerovo State University

Rhodium nitromonoethylenediamine complexes with compositions K[Rh(en)(NO2)4] (I), (Me4N)[Rh(en)(NO2)4]⋅2H2O (II), [Rh(en)(H2O)(NO2)3]⋅H2O (III), [Rh(en)(H2O)(NO2)3]⋅0.5H2O (IV), [Rh(H2O)5NO2](NO3)2 (V), K2[Rh(en)(NO2)4]NO2 (VI) are prepared and structurally characterized. Unusual lability of rhodium(III) nitroethylenediamine complexes is established upon recrystallization from hot water.

Vorobyeva S.N. , Baidina I.A. , Sukhikh T.S. , Korolkov I.V. , Belyaev A.V.
THE PREPARATION OF RHODIUM(III) NITRITE COMPLEXES WITH ETHYLENEDIAMINE
Journal of Structural Chemistry. 2022. V.63. N4. P.569-579. DOI: 10.1134/S0022476622040072 WOS Scopus РИНЦ OpenAlex

Воробьева С.Н. , Байдина И.А. , Сухих Т.С. , Корольков И.В. , Беляев А.В.
ПОЛУЧЕНИЕ НИТРИТНЫХ КОМПЛЕКСОВ РОДИЯ(III) С ЭТИЛЕНДИАМИНОМ
Журнал структурной химии. 2022. Т.63. №3. С.479-490. DOI: 10.26902/JSC_id90375 РИНЦ OpenAlex

Web of science:	WOS:000812287600007
Scopus:	2-s2.0-85132277356
Elibrary:	48720628
OpenAlex:	W4283011715

DB	Citing
Web of science	1
Scopus	1
Elibrary	1
OpenAlex	1