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XPS experimental and DFT investigations on solid solutions of Mo1−xRexS2 (0 < x < 0.20) Научная публикация

Журнал Nanoscale
ISSN: 2040-3372 , E-ISSN: 2040-3364
Вых. Данные Год: 2018, Том: 10, Номер: 21, Страницы: 10232-10240 Страниц : 9 DOI: 10.1039/c8nr01661e
Авторы Dalmatova Svetlana A. 1,2 , Fedorenko Anastasiya D. 1 , Mazalov Lev N. 1,2 , Asanov Igor P. 1,2 , Ledneva Alexandra Yu. 1 , Tarasenko Mariya S. 1 , Enyashin Andrey N. 3 , Zaikovskii Vladimir I. 2,4 , Fedorov Vladimir E. 1,2
Организации
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Prospect Acad. Lavrentieva, 3, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russia
3 Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Pervomayskaya Str., 91, Ekaterinburg 620990, Russia
4 Boreskov Institute of Catalysis Siberian Branch of the Russian Academy of Sciences, Prospect Acad. Lavrentieva, 5, Novosibirsk 630090, Russia

Реферат: The synthesis, characterization, experimental X-ray photoelectron spectra (XPS) and density-functional theory (DFT) investigations on solid solutions of Mo1−xRexS2 (x = 0.05, 0.10, 0.15 and 0.20) are reported herein. It is shown that even at a low concentration of dopant Re atoms, clustering occurs. At an Re concentration of 5% the formation of dimer-like impregnations is observed. An increase in the dopant concentration leads to an increase in the amount of clustered rhenium atoms and to the formation of rhombic clusters. The absence of magnetism within the studied Mo1−xRexS2 solid solutions allowed us to suggest a mechanism for the distribution of rhenium inside molybdenum disulphide through the initial formation of rhenium disulphide and its subsequent spreading.
Библиографическая ссылка: Dalmatova S.A. , Fedorenko A.D. , Mazalov L.N. , Asanov I.P. , Ledneva A.Y. , Tarasenko M.S. , Enyashin A.N. , Zaikovskii V.I. , Fedorov V.E.
XPS experimental and DFT investigations on solid solutions of Mo1−xRexS2 (0 < x < 0.20)
Nanoscale. 2018. V.10. N21. P.10232-10240. DOI: 10.1039/c8nr01661e WOS Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 27 февр. 2018 г.
Принята к публикации: 7 мар. 2018 г.
Опубликована online: 7 мая 2018 г.
Опубликована в печати: 7 июл. 2018 г.
Идентификаторы БД:
Web of science: WOS:000434313200047
Scopus: 2-s2.0-85047931026
РИНЦ: 35756072
OpenAlex: W2800156410
Цитирование в БД:
БД Цитирований
OpenAlex 27
Web of science 27
Scopus 26
РИНЦ 28
Альметрики: