Structural diversity of low-dimensional compounds in [M(en)2]2+/[Re6Q8(CN)6]4– systems (M = Mn, Ni, Cu)

Structural diversity of low-dimensional compounds in [M(en)2]2+/[Re6Q8(CN)6]4– systems (M = Mn, Ni, Cu) Full article

Journal

European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682

Output data

Year: 2005, Number: 3, Pages: 461-466 Pages count : 6 DOI: 10.1002/ejic.200400391

Authors

Brylev Konstantin A. ¹ , Pilet Guillaume ² , Naumov Nikolai G. ¹ , Perrin Andre ² , Fedorov Vladimir E. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
2	Institut de Chimie de Rennes, Laboratoire de Chimie du Solide et Inorganique Mole´culaire, UMR 6511 CNRS - Universite´ de Rennes 1

Abstract Five new octahedral chalcocyanide cluster compounds [{Mn(H2O)(en)2}{Mn(en)2}Re6Te8(CN)6]·3H2O (1), [Ni(NH3)2(en)2]2[{Ni(NH3)4}Re6Se8(CN)6]Cl2·2H2O (2), [Ni(NH3)2(en)2]2[{Ni(NH3)4}Re6Te8(CN)6]Cl2·H2O (3), (NH4)2[{Ni(en)2}3{Re6Te8(CN)6}2]·6H2O (4) and (Et4N)2[Cu(NH3)(en)2]2[{Cu(en)2}{Re6Te8(CN)6}2]·2H2O (5) (en = ethylenediamine), have been synthesised. All five compounds have been characterised by single-crystal X-ray diffraction analysis. Compounds 1−3 have chain-like polymeric structures, whereas compound 4 exhibits a two-dimensional polymeric structure, with negatively charged [{Ni(en)2}3{Re6Te8(CN)6}2]2−∞∞ layers, and compound 5 has an ionic structure where anionic [{Cu(en)2}{Re6Te8(CN)6}2]6− dimers are packed with cationic [Cu(NH3)(en)2]2+ complexes and Et4N+ cations.

Brylev K. , Pilet G. , Naumov N. , Perrin A. , Fedorov V.
Structural diversity of low-dimensional compounds in [M(en)2]2+/[Re6Q8(CN)6]4– systems (M = Mn, Ni, Cu)
European Journal of Inorganic Chemistry. 2005. N3. P.461-466. DOI: 10.1002/ejic.200400391 WOS Scopus РИНЦ OpenAlex

Submitted:	May 5, 2004
Published online:	Dec 6, 2004

Web of science:	WOS:000227172500002
Scopus:	2-s2.0-14544282843
Elibrary:	13497005
OpenAlex:	W2057859047

DB	Citing
Web of science	50
Scopus	48
Elibrary	50
OpenAlex	41