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Structural diversity of low-dimensional compounds in [M(en)2]2+/[Re6Q8(CN)6]4– systems (M = Mn, Ni, Cu) Научная публикация

Журнал European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682
Вых. Данные Год: 2005, Номер: 3, Страницы: 461-466 Страниц : 6 DOI: 10.1002/ejic.200400391
Авторы Brylev Konstantin A. 1 , Pilet Guillaume 2 , Naumov Nikolai G. 1 , Perrin Andre 2 , Fedorov Vladimir E. 1
Организации
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
2 Institut de Chimie de Rennes, Laboratoire de Chimie du Solide et Inorganique Mole´culaire, UMR 6511 CNRS - Universite´ de Rennes 1

Реферат: Abstract Five new octahedral chalcocyanide cluster compounds [{Mn(H2O)(en)2}{Mn(en)2}Re6Te8(CN)6]·3H2O (1), [Ni(NH3)2(en)2]2[{Ni(NH3)4}Re6Se8(CN)6]Cl2·2H2O (2), [Ni(NH3)2(en)2]2[{Ni(NH3)4}Re6Te8(CN)6]Cl2·H2O (3), (NH4)2[{Ni(en)2}3{Re6Te8(CN)6}2]·6H2O (4) and (Et4N)2[Cu(NH3)(en)2]2[{Cu(en)2}{Re6Te8(CN)6}2]·2H2O (5) (en = ethylenediamine), have been synthesised. All five compounds have been characterised by single-crystal X-ray diffraction analysis. Compounds 1−3 have chain-like polymeric structures, whereas compound 4 exhibits a two-dimensional polymeric structure, with negatively charged [{Ni(en)2}3{Re6Te8(CN)6}2]2−∞∞ layers, and compound 5 has an ionic structure where anionic [{Cu(en)2}{Re6Te8(CN)6}2]6− dimers are packed with cationic [Cu(NH3)(en)2]2+ complexes and Et4N+ cations.
Библиографическая ссылка: Brylev K. , Pilet G. , Naumov N. , Perrin A. , Fedorov V.
Structural diversity of low-dimensional compounds in [M(en)2]2+/[Re6Q8(CN)6]4– systems (M = Mn, Ni, Cu)
European Journal of Inorganic Chemistry. 2005. N3. P.461-466. DOI: 10.1002/ejic.200400391 WOS Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 5 мая 2004 г.
Опубликована online: 6 дек. 2004 г.
Идентификаторы БД:
Web of science: WOS:000227172500002
Scopus: 2-s2.0-14544282843
РИНЦ: 13497005
OpenAlex: W2057859047
Цитирование в БД:
БД Цитирований
Web of science 50
Scopus 48
РИНЦ 50
OpenAlex 41
Альметрики: