Structural diversity of low-dimensional compounds in [M(en)2]2+/[Re6Q8(CN)6]4– systems (M = Mn, Ni, Cu) Научная публикация
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European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682 |
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| Вых. Данные | Год: 2005, Номер: 3, Страницы: 461-466 Страниц : 6 DOI: 10.1002/ejic.200400391 | ||||
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Реферат:
Abstract Five new octahedral chalcocyanide cluster compounds [{Mn(H2O)(en)2}{Mn(en)2}Re6Te8(CN)6]·3H2O (1), [Ni(NH3)2(en)2]2[{Ni(NH3)4}Re6Se8(CN)6]Cl2·2H2O (2), [Ni(NH3)2(en)2]2[{Ni(NH3)4}Re6Te8(CN)6]Cl2·H2O (3), (NH4)2[{Ni(en)2}3{Re6Te8(CN)6}2]·6H2O (4) and (Et4N)2[Cu(NH3)(en)2]2[{Cu(en)2}{Re6Te8(CN)6}2]·2H2O (5) (en = ethylenediamine), have been synthesised. All five compounds have been characterised by single-crystal X-ray diffraction analysis. Compounds 1−3 have chain-like polymeric structures, whereas compound 4 exhibits a two-dimensional polymeric structure, with negatively charged [{Ni(en)2}3{Re6Te8(CN)6}2]2−∞∞ layers, and compound 5 has an ionic structure where anionic [{Cu(en)2}{Re6Te8(CN)6}2]6− dimers are packed with cationic [Cu(NH3)(en)2]2+ complexes and Et4N+ cations.
Библиографическая ссылка:
Brylev K.
, Pilet G.
, Naumov N.
, Perrin A.
, Fedorov V.
Structural diversity of low-dimensional compounds in [M(en)2]2+/[Re6Q8(CN)6]4– systems (M = Mn, Ni, Cu)
European Journal of Inorganic Chemistry. 2005. N3. P.461-466. DOI: 10.1002/ejic.200400391 WOS Scopus РИНЦ OpenAlex
Structural diversity of low-dimensional compounds in [M(en)2]2+/[Re6Q8(CN)6]4– systems (M = Mn, Ni, Cu)
European Journal of Inorganic Chemistry. 2005. N3. P.461-466. DOI: 10.1002/ejic.200400391 WOS Scopus РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 5 мая 2004 г. |
| Опубликована online: | 6 дек. 2004 г. |
Идентификаторы БД:
| Web of science: | WOS:000227172500002 |
| Scopus: | 2-s2.0-14544282843 |
| РИНЦ: | 13497005 |
| OpenAlex: | W2057859047 |