New complex compounds based on [Re6Te8(CN)6]4– cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: adjustment of the crystal structure by the blocking of coordination sites

New complex compounds based on [Re6Te8(CN)6]4– cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: adjustment of the crystal structure by the blocking of coordination sites Full article

Journal

Журнал структурной химии
ISSN: 2542-0976 , E-ISSN: 0136-7463

Output data

Year: 2005, Volume: 46, Number: Supplement, Pages: S127-S133 Pages count :

Authors

Brylev K.A. ¹ , Naumov N.G. ¹ , Fedorov V.E. ¹ , Ibers J.A. ²

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
2	Department of Chemistry, Northwestern University

Three new octahedral ionic rhenium tellurocyanide cluster compounds [Co(dien)2]2[Re6Te8(CN)6]·4H2O (1), [Cu(dien)2]2[Re6Te8(CN)6]·4H2O (2), and [Co(dien)2]3[Re6Te8(CN)6]Br2·H2O (3) (dien = diethylenetriamine) have been obtained by the diffusion of an ammonia solution of Cs4[Re6Te8(CN)6]·2H2O into a glycerol solution of COCl2·6H2O (for 1 and 3) or CuCl2·2H2O (for 2) in the presence of dien. The compounds have been characterized by single-crystal X-ray diffraction methods and by elemental analyses.

Brylev K.A. , Naumov N.G. , Fedorov V.E. , Ibers J.A.
New complex compounds based on [Re6Te8(CN)6]4– cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: adjustment of the crystal structure by the blocking of coordination sites
Журнал структурной химии. 2005. Т.46. №Supplement. С.S127-S133.

Brylev K.A. , Naumov N.G. , Fedorov V.E. , Ibers J.A.
New complex compounds based on [Re6Te8(CN)6]4− cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: Adjustment of the crystal structure by the blocking of coordination sites
Journal of Structural Chemistry. 2005. V.46. NS1. P.S130-S136. DOI: 10.1007/s10947-006-0163-5 WOS Scopus РИНЦ OpenAlex

Submitted:	Dec 14, 2004
Published online:	Jan 15, 2005

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