New complex compounds based on [Re6Te8(CN)6]4− cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: Adjustment of the crystal structure by the blocking of coordination sites Full article
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Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Output data | Year: 2005, Volume: 46, Number: S1, Pages: S130-S136 Pages count : DOI: 10.1007/s10947-006-0163-5 | ||||
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Abstract:
Three new octahedral ionic rhenium tellurocyanide cluster compounds [Co(dien)2]2[Re6Te8(CN)6]·4H2O (1), [Cu(dien)2]2[Re6Te8(CN)6]·4H2O (2), and [Co(dien)2]3[Re6Te8(CN)6]Br2·H2O (3) (dien = diethylenetriamine) have been obtained by the diffusion of an ammonia solution of Cs4[Re6Te8(CN)6]·2H2O into a glycerol solution of COCl2·6H2O (for 1 and 3) or CuCl2·2H2O (for 2) in the presence of dien. The compounds have been characterized by single-crystal X-ray diffraction methods and by elemental analyses.
Cite:
Brylev K.A.
, Naumov N.G.
, Fedorov V.E.
, Ibers J.A.
New complex compounds based on [Re6Te8(CN)6]4− cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: Adjustment of the crystal structure by the blocking of coordination sites
Journal of Structural Chemistry. 2005. V.46. NS1. P.S130-S136. DOI: 10.1007/s10947-006-0163-5 WOS Scopus РИНЦ OpenAlex
New complex compounds based on [Re6Te8(CN)6]4− cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: Adjustment of the crystal structure by the blocking of coordination sites
Journal of Structural Chemistry. 2005. V.46. NS1. P.S130-S136. DOI: 10.1007/s10947-006-0163-5 WOS Scopus РИНЦ OpenAlex
Original:
Brylev K.A.
, Naumov N.G.
, Fedorov V.E.
, Ibers J.A.
New complex compounds based on [Re6Te8(CN)6]4– cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: adjustment of the crystal structure by the blocking of coordination sites
Журнал структурной химии. 2005. Т.46. №Supplement. С.S127-S133.
New complex compounds based on [Re6Te8(CN)6]4– cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: adjustment of the crystal structure by the blocking of coordination sites
Журнал структурной химии. 2005. Т.46. №Supplement. С.S127-S133.
Dates:
| Submitted: | Dec 14, 2004 |
| Published online: | Jan 15, 2005 |
Identifiers:
| Web of science: | WOS:000240205600021 |
| Scopus: | 2-s2.0-33745676970 |
| Elibrary: | 23975465 |
| OpenAlex: | W2074330067 |