Carbon Nanofibers Synthesized at Different Pressures for Detection of NO2 at Room Temperature

Carbon Nanofibers Synthesized at Different Pressures for Detection of NO2 at Room Temperature Научная публикация

Журнал

Chemosensors
ISSN: 2227-9040

Вых. Данные

Год: 2023, Том: 11, Номер: 7, Номер статьи : 381, Страниц : 17 DOI: 10.3390/chemosensors11070381

Ключевые слова

gas sensors; carbon nanofibers; nitrogen dioxide; ammonia; adsorption; response

Авторы

Lapekin Nikita I. ¹ , Kurmashov Pavel B. ¹ , Larina Tatyana V. ² , Chesalov Yurii A. ² , Kurdyumov Dmitry S. ¹ , Ukhina Arina V. ³ , Maksimovskiy Evgene A. ⁴ , Ishchenko Arcady V. ² , Sysoev Vitalii I. ⁴ , Bannov Alexander G. ¹

Организации

1	Department of Chemistry and Chemical Engineering, Novosibirsk State Technical University, 630073 Novosibirsk, Russia
2	Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, 630090 Novosibirsk, Russia
3	Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of Russian Academy of Sciences, 630128 Novosibirsk, Russia
4	Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 630090 Novosibirsk, Russia

In this paper, room-temperature chemiresistive gas sensors for NO2 detection based on CVD-grown carbon nanofibers (CNFs) were investigated. Transmission electron microscopy, low-temperature nitrogen adsorption, and X-ray diffraction were used to investigate the carbon nanomaterials. CNFs were synthesized in a wide range of pressure (1–5 bar) by COx-free decomposition of methane over the Ni/Al2O3 catalyst. It was found that the increase in pressure during the synthesis of CNFs induced the later deactivation of the catalyst, and the yield of CNFs decreased when increasing pressure. Sensing properties were determined in a dynamic flow-through installation at NO2 concentrations ranging from 1 to 400 ppm. Ammonia detection was tested for comparison in a range of 100–500 ppm. The obtained sensors based on CNFs synthesized at 1 bar showed high responses of 1.7%, 5.0%, and 10.0% to 1 ppm, 5 ppm, and 10 ppm NO2 at 25 ± 2 °C, respectively. It was shown that the obtained non-modified carbon nanomaterials can be used successfully used for room temperature detection of nitrogen dioxide. It was found that the increase in relative humidity (RH) of air induced growth of response, and this effect was facilitated after reaching RH ~35% for CNFs synthesized at elevated pressures.

Lapekin N.I. , Kurmashov P.B. , Larina T.V. , Chesalov Y.A. , Kurdyumov D.S. , Ukhina A.V. , Maksimovskiy E.A. , Ishchenko A.V. , Sysoev V.I. , Bannov A.G.
Carbon Nanofibers Synthesized at Different Pressures for Detection of NO2 at Room Temperature
Chemosensors. 2023. V.11. N7. 381 :1-17. DOI: 10.3390/chemosensors11070381 WOS Scopus РИНЦ OpenAlex

Поступила в редакцию:	30 мар. 2023 г.
Принята к публикации:	5 июл. 2023 г.
Опубликована online:	7 июл. 2023 г.
Опубликована в печати:	10 окт. 2023 г.

Web of science:	WOS:001038163100001
Scopus:	2-s2.0-85166289335
РИНЦ:	54372732
OpenAlex:	W4383722108

БД	Цитирований
Web of science	1
Scopus	2
РИНЦ	1
OpenAlex	2