Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid Full article
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Output data | Year: 2018, Volume: 67, Number: 3, Pages: 490-496 Pages count : 7 DOI: 10.1007/s11172-018-2098-3 | ||||
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Abstract:
Three new metal-organic coordination polymers were obtained namely, [Mn3(chdc)3-(NMP)2(DMF)2] (1, chdc2– is trans-1,4-cyclohexanedicarboxylate, NMP is N-methylpyrrolidone, DMF is N,N-dimethylformamide), [Zn3(chdc)3(NMP)2]•2NMP (2), and [Zn3(chdc)3(ur)-(DMF)0.5]•DMF (3, ur is the urotropine). The crystal structures of polymers 1, 2, and 3 were determined by single-crystal X-ray crystallography. All three compounds were found to contain a trinuclear secondary building unit {M3(OOC)6}. Coordination polymers 1 and 2 have a layered structure, while polymer 3 has a three-dimensional coordination framework with isolated pores formed due to the presence of urotropine bridging molecules. Compounds 1 and 3 were characterized by IR spectroscopy, thermogravimetric and elemental analysis data, powder X-ray diffraction. Compound 3 was also characterized by UV-Vis diffuse reflectance spectrum.
Cite:
Demakov P.A.
, Sapchenko S.A.
, Samsonenko D.G.
, Dybtsev D.N.
, Fedin V.P.
Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid
Russian Chemical Bulletin. 2018. V.67. N3. P.490-496. DOI: 10.1007/s11172-018-2098-3 WOS Scopus РИНЦ OpenAlex
Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid
Russian Chemical Bulletin. 2018. V.67. N3. P.490-496. DOI: 10.1007/s11172-018-2098-3 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Oct 1, 2017 |
| Published print: | Jun 25, 2018 |
Identifiers:
| Web of science: | WOS:000436260900013 |
| Scopus: | 2-s2.0-85049313646 |
| Elibrary: | 35755797 |
| OpenAlex: | W2810792937 |