Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid

Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2018, Том: 67, Номер: 3, Страницы: 490-496 Страниц : 7 DOI: 10.1007/s11172-018-2098-3

Авторы

Demakov P.A. ^1,2 , Sapchenko S.A. ^1,2 , Samsonenko D.G. ^1,2 , Dybtsev D.N. ^1,2 , Fedin V.P. ^1,2

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentґeva, 630090, Novosibirsk, Russian Federation
2	Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

Three new metal-organic coordination polymers were obtained namely, [Mn3(chdc)3-(NMP)2(DMF)2] (1, chdc2– is trans-1,4-cyclohexanedicarboxylate, NMP is N-methylpyrrolidone, DMF is N,N-dimethylformamide), [Zn3(chdc)3(NMP)2]•2NMP (2), and [Zn3(chdc)3(ur)-(DMF)0.5]•DMF (3, ur is the urotropine). The crystal structures of polymers 1, 2, and 3 were determined by single-crystal X-ray crystallography. All three compounds were found to contain a trinuclear secondary building unit {M3(OOC)6}. Coordination polymers 1 and 2 have a layered structure, while polymer 3 has a three-dimensional coordination framework with isolated pores formed due to the presence of urotropine bridging molecules. Compounds 1 and 3 were characterized by IR spectroscopy, thermogravimetric and elemental analysis data, powder X-ray diffraction. Compound 3 was also characterized by UV-Vis diffuse reflectance spectrum.

Demakov P.A. , Sapchenko S.A. , Samsonenko D.G. , Dybtsev D.N. , Fedin V.P.
Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid
Russian Chemical Bulletin. 2018. V.67. N3. P.490-496. DOI: 10.1007/s11172-018-2098-3 WOS Scopus РИНЦ OpenAlex

Поступила в редакцию:	1 окт. 2017 г.
Опубликована в печати:	25 июн. 2018 г.

Web of science:	WOS:000436260900013
Scopus:	2-s2.0-85049313646
РИНЦ:	35755797
OpenAlex:	W2810792937

БД	Цитирований
Web of science	21
Scopus	22
РИНЦ	23
OpenAlex	23