First Example of Coordination Polymer Based on the Tetrahedral Cluster Cyano Complex of Rhenium and Barium Full article
| Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
||
|---|---|---|---|
| Output data | Year: 2025, Volume: 51, Number: 8, Pages: 718-722 Pages count : 5 DOI: 10.1134/S1070328425600597 | ||
| Tags | rhenium, tetrahedral cluster complex, cyanides, barium, crystal structure | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The reaction of the anionic tetrahedral cluster rhenium complex [Re4(AsO)4(CN)12]8– with Ba2+ is studied. Under the hydrothermal conditions, the reaction affords the framework coordination polymer [{Ba4(H2O)9}Re4(AsO)4(CN)12]·15H2O (I). The coordination polymer is formed from cluster anions [Re4(AsO)4(CN)12]8– and cationic fragments [{Ba4(H2O}9]8+ linked by CN– bridges. The synthesized compound is characterized by single-crystal X-ray diffraction (XRD) (CIF file CCDC no. 2441985), powder XRD, IR spectroscopy, and elemental analysis.
Cite:
Ermolaev A.V.
, Mironov Y.V.
First Example of Coordination Polymer Based on the Tetrahedral Cluster Cyano Complex of Rhenium and Barium
Russian Journal of Coordination Chemistry. 2025. V.51. N8. P.718-722. DOI: 10.1134/S1070328425600597
First Example of Coordination Polymer Based on the Tetrahedral Cluster Cyano Complex of Rhenium and Barium
Russian Journal of Coordination Chemistry. 2025. V.51. N8. P.718-722. DOI: 10.1134/S1070328425600597
Dates:
| Submitted: | Apr 14, 2025 |
| Accepted: | Jun 13, 2025 |
Identifiers:
No identifiers
Citing:
Пока нет цитирований