First Example of Coordination Polymer Based on the Tetrahedral Cluster Cyano Complex of Rhenium and Barium

First Example of Coordination Polymer Based on the Tetrahedral Cluster Cyano Complex of Rhenium and Barium Научная публикация

Журнал

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Вых. Данные

Год: 2025, Том: 51, Номер: 8, Страницы: 718-722 Страниц : 5 DOI: 10.1134/S1070328425600597

Ключевые слова

rhenium, tetrahedral cluster complex, cyanides, barium, crystal structure

Авторы

Ermolaev A.V. ¹ , Mironov Yu.V. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

The reaction of the anionic tetrahedral cluster rhenium complex [Re4(AsO)4(CN)12]8– with Ba2+ is studied. Under the hydrothermal conditions, the reaction affords the framework coordination polymer [{Ba4(H2O)9}Re4(AsO)4(CN)12]·15H2O (I). The coordination polymer is formed from cluster anions [Re4(AsO)4(CN)12]8– and cationic fragments [{Ba4(H2O}9]8+ linked by CN– bridges. The synthesized compound is characterized by single-crystal X-ray diffraction (XRD) (CIF file CCDC no. 2441985), powder XRD, IR spectroscopy, and elemental analysis.

Ermolaev A.V. , Mironov Y.V.
First Example of Coordination Polymer Based on the Tetrahedral Cluster Cyano Complex of Rhenium and Barium
Russian Journal of Coordination Chemistry. 2025. V.51. N8. P.718-722. DOI: 10.1134/S1070328425600597 WOS

Поступила в редакцию:	14 апр. 2025 г.
Принята к публикации:	13 июн. 2025 г.

Web of science:

WOS:001618362400011

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