Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 with triphenylphosphine

Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 with triphenylphosphine Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2000, Volume: 49, Number: 4, Pages: 747-752 Pages count : 6 DOI: 10.1007/bf02495496

Authors

Maksakov V.A. ¹ , Slovokhotova I.V. ¹ , Babailov S.P. ¹

Affiliations

1	Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Photolysis of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 together with PPh3 results in replacement of the CO groups by PPh3 both at the Mn atom and in the Os3 metallocycle to afford the complexes (μ-H)Os3{μ-O2CC5H4Mn(CO)2PPh3}(CO)10, (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)9}(CO)9PPh3, and (μ-H)Os3{μ-O2CC5H4Mn(CO)2PPh3}(CO)9PPh3 (two isomers). The reaction is also accompanied by the partial removal of the Mn(CO)3 group followed by the protonation of the cyclopentadienyl group and formation of triosmium clusters (μ-H)Os3(μ-O2CC5H4R}(CO)10 (R=H, Et).

Maksakov V.A. , Slovokhotova I.V. , Babailov S.P.
Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 with triphenylphosphine
Russian Chemical Bulletin. 2000. V.49. N4. P.747-752. DOI: 10.1007/bf02495496 Scopus OpenAlex

Published print:

Jan 2, 2000

Scopus:	2-s2.0-0034343859
OpenAlex:	W1972218544

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