Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 with triphenylphosphine Научная публикация
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Вых. Данные | Год: 2000, Том: 49, Номер: 4, Страницы: 747-752 Страниц : 6 DOI: 10.1007/bf02495496 | ||
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Реферат:
Photolysis of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 together with PPh3 results in replacement of the CO groups by PPh3 both at the Mn atom and in the Os3 metallocycle to afford the complexes (μ-H)Os3{μ-O2CC5H4Mn(CO)2PPh3}(CO)10, (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)9}(CO)9PPh3, and (μ-H)Os3{μ-O2CC5H4Mn(CO)2PPh3}(CO)9PPh3 (two isomers). The reaction is also accompanied by the partial removal of the Mn(CO)3 group followed by the protonation of the cyclopentadienyl group and formation of triosmium clusters (μ-H)Os3(μ-O2CC5H4R}(CO)10 (R=H, Et).
Библиографическая ссылка:
Maksakov V.A.
, Slovokhotova I.V.
, Babailov S.P.
Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 with triphenylphosphine
Russian Chemical Bulletin. 2000. V.49. N4. P.747-752. DOI: 10.1007/bf02495496 Scopus OpenAlex
Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3}(CO)10 with triphenylphosphine
Russian Chemical Bulletin. 2000. V.49. N4. P.747-752. DOI: 10.1007/bf02495496 Scopus OpenAlex
Даты:
| Опубликована в печати: | 2 янв. 2000 г. |
Идентификаторы БД:
| Scopus: | 2-s2.0-0034343859 |
| OpenAlex: | W1972218544 |