Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene

Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2024, Volume: 50, Number: 9, Pages: 662-672 Pages count : 11 DOI: 10.1134/S1070328424600578

Tags

complexes, manganese, bis(imino)acenaphthenes (BIANs), synthesis, X-ray diffraction, quantum chemical calculations

Authors

Laricheva Yu.A. ¹ , Guan Ch ² , Kuratieva N.V. ¹ , Romashev N.F. ¹ , Gushchin A.L. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk National Research State University, Novosibirsk, Russia

Methods for the synthesis of new manganese(II) complexes with N,N'-bis[(2,4,6-trimethylphenyl)iminoacenaphthene (Tmp-bian), [Mn(Tmp-bian)Br2] (I), [Mn(Tmp-bian)(EtOH)Br2] (Ia), [Mn(Tmp-bian)Cl2] (II), [Mn(Tmp-bian)2(ClO4)2] (III), and [Mn(Tmp-bian)2(OTs)2] (IV) were developed. The obtained compounds were characterized by elemental analysis and IR spectroscopy. The molecular structures of I, Iа, and III were determined by X-ray diffraction (CCDC no. 233510–233512). The electronic structures of I and III were established by quantum chemical calculations using density functional theory (DFT).

Laricheva Y.A. , Guan C. , Kuratieva N.V. , Romashev N.F. , Gushchin A.L.
Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene
Russian Journal of Coordination Chemistry. 2024. V.50. N9. P.662-672. DOI: 10.1134/S1070328424600578

Submitted:	Feb 28, 2024
Accepted:	Apr 2, 2024
Published print:	Sep 30, 2024

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