Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene

Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene Научная публикация

Журнал

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Вых. Данные

Год: 2024, Том: 50, Номер: 9, Страницы: 662-672 Страниц : 11 DOI: 10.1134/S1070328424600578

Ключевые слова

complexes, manganese, bis(imino)acenaphthenes (BIANs), synthesis, X-ray diffraction, quantum chemical calculations

Авторы

Laricheva Yu.A. ¹ , Guan Ch ² , Kuratieva N.V. ¹ , Romashev N.F. ¹ , Gushchin A.L. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk National Research State University, Novosibirsk, Russia

Methods for the synthesis of new manganese(II) complexes with N,N'-bis[(2,4,6-trimethylphenyl)iminoacenaphthene (Tmp-bian), [Mn(Tmp-bian)Br2] (I), [Mn(Tmp-bian)(EtOH)Br2] (Ia), [Mn(Tmp-bian)Cl2] (II), [Mn(Tmp-bian)2(ClO4)2] (III), and [Mn(Tmp-bian)2(OTs)2] (IV) were developed. The obtained compounds were characterized by elemental analysis and IR spectroscopy. The molecular structures of I, Iа, and III were determined by X-ray diffraction (CCDC no. 233510–233512). The electronic structures of I and III were established by quantum chemical calculations using density functional theory (DFT).

Laricheva Y.A. , Guan C. , Kuratieva N.V. , Romashev N.F. , Gushchin A.L.
Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene
Russian Journal of Coordination Chemistry. 2024. Т.50. №9. С.662-672. DOI: 10.1134/S1070328424600578

Поступила в редакцию:	28 февр. 2024 г.
Принята к публикации:	2 апр. 2024 г.
Опубликована в печати:	30 сент. 2024 г.

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