Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene Научная публикация
Журнал |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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Вых. Данные | Год: 2024, Том: 50, Номер: 9, Страницы: 662-672 Страниц : 11 DOI: 10.1134/S1070328424600578 | ||||
Ключевые слова | complexes, manganese, bis(imino)acenaphthenes (BIANs), synthesis, X-ray diffraction, quantum chemical calculations | ||||
Авторы |
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Организации |
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Реферат:
Methods for the synthesis of new manganese(II) complexes with N,N'-bis[(2,4,6-trimethylphenyl)iminoacenaphthene (Tmp-bian), [Mn(Tmp-bian)Br2] (I), [Mn(Tmp-bian)(EtOH)Br2] (Ia), [Mn(Tmp-bian)Cl2] (II), [Mn(Tmp-bian)2(ClO4)2] (III), and [Mn(Tmp-bian)2(OTs)2] (IV) were developed. The obtained compounds were characterized by elemental analysis and IR spectroscopy. The molecular structures of I, Iа, and III were determined by X-ray diffraction (CCDC no. 233510–233512). The electronic structures of I and III were established by quantum chemical calculations using density functional theory (DFT).
Библиографическая ссылка:
Laricheva Y.A.
, Guan C.
, Kuratieva N.V.
, Romashev N.F.
, Gushchin A.L.
Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene
Russian Journal of Coordination Chemistry. 2024. V.50. N9. P.662-672. DOI: 10.1134/S1070328424600578
Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene
Russian Journal of Coordination Chemistry. 2024. V.50. N9. P.662-672. DOI: 10.1134/S1070328424600578
Даты:
Поступила в редакцию: | 28 февр. 2024 г. |
Принята к публикации: | 2 апр. 2024 г. |
Опубликована в печати: | 30 сент. 2024 г. |
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