XANES investigation of manganese sulfide solid solutions

XANES investigation of manganese sulfide solid solutions ArticleGenre_short.SHORT_COMMUNICATION

Journal

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
ISSN: 1386-1425 , E-ISSN: 1873-3557

Output data

Year: 2018, Volume: 205, Pages: 593-596 Pages count : 4 DOI: 10.1016/j.saa.2018.07.053

Tags

Manganese sulfide, Variable valence, XES, XANES, FDMNES, Finite difference method

Authors

Syrokvashin M.M. ¹ , Korotaev E.V. ¹ , Filatova I.Yu. ¹ , Trubina S.V. ¹ , Erenburg S.B. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia

A comprehensive study of the valence state and the local coordination character of Mn1−xYbxS (x= 0; 0.01; 0.05) solid solutions has been performed using X-ray absorption spectroscopy combined with finite difference method calculations. The good agreement between experimental and calculated data indicates that cationic substitution does not lead to significant changes in the manganese local coordination character. The ytterbium atoms are found to be in the trivalent state, while the manganese and sulfur atoms are in the divalent state.

Syrokvashin M.M. , Korotaev E.V. , Filatova I.Y. , Trubina S.V. , Erenburg S.B.
XANES investigation of manganese sulfide solid solutions
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2018. V.205. P.593-596. DOI: 10.1016/j.saa.2018.07.053 Scopus OpenAlex

Scopus:	2-s2.0-85050820856
OpenAlex:	W2884161954

DB	Citing
OpenAlex	6
Scopus	8