XANES investigation of manganese sulfide solid solutions | Sciact

XANES investigation of manganese sulfide solid solutions Краткое сообщение

Журнал

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
ISSN: 1386-1425 , E-ISSN: 1873-3557

Вых. Данные

Год: 2018, Том: 205, Страницы: 593-596 Страниц : 4 DOI: 10.1016/j.saa.2018.07.053

Ключевые слова

Manganese sulfide, Variable valence, XES, XANES, FDMNES, Finite difference method

Авторы

Syrokvashin M.M. ¹ , Korotaev E.V. ¹ , Filatova I.Yu. ¹ , Trubina S.V. ¹ , Erenburg S.B. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia

A comprehensive study of the valence state and the local coordination character of Mn1−xYbxS (x= 0; 0.01; 0.05) solid solutions has been performed using X-ray absorption spectroscopy combined with finite difference method calculations. The good agreement between experimental and calculated data indicates that cationic substitution does not lead to significant changes in the manganese local coordination character. The ytterbium atoms are found to be in the trivalent state, while the manganese and sulfur atoms are in the divalent state.

Syrokvashin M.M. , Korotaev E.V. , Filatova I.Y. , Trubina S.V. , Erenburg S.B.
XANES investigation of manganese sulfide solid solutions
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2018. V.205. P.593-596. DOI: 10.1016/j.saa.2018.07.053 WOS Scopus OpenAlex

Web of science:	WOS:000445713600070
Scopus:	2-s2.0-85050820856
OpenAlex:	W2884161954

БД	Цитирований
OpenAlex	6
Scopus	8
Web of science	6