Photocatalytic H2 generation from ethanol and glucose aqueous solutions by PtOx/TiO2 composites

Photocatalytic H2 generation from ethanol and glucose aqueous solutions by PtOx/TiO2 composites Научная публикация

Журнал

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Вых. Данные

Год: 2023, Том: 48, Номер: 59, Страницы: 22366-22378 Страниц : 13 DOI: 10.1016/j.ijhydene.2022.11.265

Авторы

Tkachenko Pavel ^1,2 , Volchek Victoria ¹ , Kurenkova Anna ^1,3 , Gerasimov Evgeny ³ , Popovetskiy Pavel ¹ , Asanov Igor ¹ , Yushina Irina ¹ , Kozlova Ekaterina ³ , Vasilchenko Danila ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, 630090 Novosibirsk, Russian Federation
2	Novosibirsk State University, 630090 Novosibirsk, Russian Federation
3	Boreskov Institute of Catalysis 630090 Novosibirsk, Russia

Информация о финансировании (1)

Российский научный фонд

21-73-10038

A new straightforward protocol for the deposition of the platinum oxide (PtO–PtO2) particles onto the TiO2 semiconductor via controllable hydrolysis of the sulfuric acid solution of Pt(IV) hydroxide was developed. The developed approach represents a simple and “green” way to prepare the supported Adams-type catalysts. In the constructed composites (PtO2·xH2O/TiO2) the Pt ionic species (hydrated PtO and PtO2 nanoparticles) weakly interact with the titania surface, but under heating the Pt–O–Ti bonds are established, resulting in the stabilization of the Pt(II) ionic state. This state dominates in the obtained catalysts PtOx/TiO2 with a low platinum loading, while at a higher Pt content the metallic Pt particles also appear. The prepared PtOx/TiO2 photocatalysts have been successfully tested in the production of hydrogen under UV light from aqueous solutions of ethanol and glucose, the products of starch biomass processing. Appreciable activity in the production of hydrogen from water/ethanol mixtures was achieved, even at a Pt content of up to 0.05%. PtOx/TiO2 photocatalysts with Pt content of 0.2–0.4 wt% have been successfully used to produce hydrogen from aqueous glucose solutions, and PtOx(0.29)/TiO2 photocatalyst has demonstrated an exceptionally high rate of H2 production per gram of platinum introduced and the quantum efficiency comparable to the highest published values.

Tkachenko P. , Volchek V. , Kurenkova A. , Gerasimov E. , Popovetskiy P. , Asanov I. , Yushina I. , Kozlova E. , Vasilchenko D.
Photocatalytic H2 generation from ethanol and glucose aqueous solutions by PtOx/TiO2 composites
International Journal of Hydrogen Energy. 2023. V.48. N59. P.22366-22378. DOI: 10.1016/j.ijhydene.2022.11.265 WOS Scopus РИНЦ OpenAlex

Поступила в редакцию:	12 окт. 2022 г.
Принята к публикации:	22 нояб. 2022 г.
Опубликована online:	15 дек. 2022 г.
Опубликована в печати:	12 июл. 2023 г.

Web of science:	WOS:001041155500001
Scopus:	2-s2.0-85144776632
РИНЦ:	54101754
OpenAlex:	W4311776020

БД	Цитирований
OpenAlex	16
Scopus	16
РИНЦ	9
Web of science	12