Metal-organic frameworks based on 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane: synthesis, structure, and properties

Metal-organic frameworks based on 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane: synthesis, structure, and properties Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2020, Volume: 69, Number: 6, Pages: 1122-1129 Pages count : 8 DOI: 10.1007/s11172-020-2877-5

Authors

Lysova A.A. ^1,2 , Marchenko R.D. ³ , Samsonenko D.G. ^1,2 , Potapov A.S. ^1,3 , Fedin V.P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation
2	Novosibirsk State University, 1 ul. Pirogova, 630090, Novosibirsk, Russian Federation
3	National Research Tomsk Polytechnic University, 30 prosp. Lenina, 634050, Tomsk, Russian Federation

Four new metal-organic frameworks were synthesized based on the N-donor ligand 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane (L) novel in this field of chemistry: three one-dimensional metal-organic frameworks based on silver(I) cations, [Ag3(L)2(NO3)2]-NO3·MeOH (1), [Ag(L)]NO3 (2), and [Ag(L)(H2O)]NO3 (3), and one three-dimensional metal-organic framework [Zn3(bdc)3(L)]·0.5 MeOH (4, H2bdc is 1,4-benzenedicarboxylic acid). Compounds 1 and 4 contain trinuclear units. In compound 1, these units are linked via the ligand L to form polymer chains. In compound 4, the ligand L bridges polymer layers, which are composed of carboxylate units {Zn3(bdc)6}, to form a three-dimensional framework. Compounds 2 and 3 are composed of mononuclear units, which are connected via the ligand L to form polymer chains. Luminescence of compound 3 was found to be due to intraligand transitions.

Lysova A.A. , Marchenko R.D. , Samsonenko D.G. , Potapov A.S. , Fedin V.P.
Metal-organic frameworks based on 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane: synthesis, structure, and properties
Russian Chemical Bulletin. 2020. V.69. N6. P.1122-1129. DOI: 10.1007/s11172-020-2877-5 WOS OpenAlex

Лысова А.А. , Марченко Р.Д. , Самсоненко Д.Г. , Потапов А.С. , Федин В.П.
Координационные полимеры на основе 1,5-бис(3,5-диметилпиразол-1-ил)-3-селенапентана: синтез, строение, свойства
Известия Академии наук. Серия химическая. 2020. №6. С.1122-1129.

Submitted:	Dec 30, 2019
Accepted:	Jan 31, 2020
Published online:	Jul 20, 2020

Web of science:	WOS:000550237500013
OpenAlex:	W3044311872

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OpenAlex	7
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