Metal-organic frameworks based on 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane: synthesis, structure, and properties

Metal-organic frameworks based on 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane: synthesis, structure, and properties Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2020, Том: 69, Номер: 6, Страницы: 1122-1129 Страниц : 8 DOI: 10.1007/s11172-020-2877-5

Авторы

Lysova A.A. ^1,2 , Marchenko R.D. ³ , Samsonenko D.G. ^1,2 , Potapov A.S. ^1,3 , Fedin V.P. ^1,2

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation
2	Novosibirsk State University, 1 ul. Pirogova, 630090, Novosibirsk, Russian Federation
3	National Research Tomsk Polytechnic University, 30 prosp. Lenina, 634050, Tomsk, Russian Federation

Four new metal-organic frameworks were synthesized based on the N-donor ligand 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane (L) novel in this field of chemistry: three one-dimensional metal-organic frameworks based on silver(I) cations, [Ag3(L)2(NO3)2]-NO3·MeOH (1), [Ag(L)]NO3 (2), and [Ag(L)(H2O)]NO3 (3), and one three-dimensional metal-organic framework [Zn3(bdc)3(L)]·0.5 MeOH (4, H2bdc is 1,4-benzenedicarboxylic acid). Compounds 1 and 4 contain trinuclear units. In compound 1, these units are linked via the ligand L to form polymer chains. In compound 4, the ligand L bridges polymer layers, which are composed of carboxylate units {Zn3(bdc)6}, to form a three-dimensional framework. Compounds 2 and 3 are composed of mononuclear units, which are connected via the ligand L to form polymer chains. Luminescence of compound 3 was found to be due to intraligand transitions.

Lysova A.A. , Marchenko R.D. , Samsonenko D.G. , Potapov A.S. , Fedin V.P.
Metal-organic frameworks based on 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane: synthesis, structure, and properties
Russian Chemical Bulletin. 2020. V.69. N6. P.1122-1129. DOI: 10.1007/s11172-020-2877-5 WOS OpenAlex

Лысова А.А. , Марченко Р.Д. , Самсоненко Д.Г. , Потапов А.С. , Федин В.П.
Координационные полимеры на основе 1,5-бис(3,5-диметилпиразол-1-ил)-3-селенапентана: синтез, строение, свойства
Известия Академии наук. Серия химическая. 2020. №6. С.1122-1129.

Поступила в редакцию:	30 дек. 2019 г.
Принята к публикации:	31 янв. 2020 г.
Опубликована online:	20 июл. 2020 г.

Web of science:	WOS:000550237500013
OpenAlex:	W3044311872

БД	Цитирований
OpenAlex	7
Web of science	7