Heterobimetallic PtII–AgI complex supported by diphenyl(2-pyrimidyl)phosphine: Synthesis and thermochromic photoluminescence

Heterobimetallic PtII–AgI complex supported by diphenyl(2-pyrimidyl)phosphine: Synthesis and thermochromic photoluminescence Full article

Journal

Inorganic Chemistry Communications
ISSN: 1387-7003 , E-ISSN: 1879-0259

Output data

Year: 2020, Volume: 115, Article number : 107862, Pages count : 4 DOI: 10.1016/j.inoche.2020.107862

Authors

Artem'ev Alexander V. ¹ , Rogovoy Maxim I. ¹ , Samsonenko Denis G. ¹ , Rakhmanova Mariana I. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation

The reaction of diphenyl(2-pyrimidyl)phosphine (L) derived complex [Pt(L)2Cl2] with AgNO3 (1:3 M ratio, respectively) results in assembly of heterobimetallic complex [AgPt(L)2(NO3)3], wherein Pt → Ag dative bond of 2.9088(2) Å is formed. This complex features thermochromic photoluminescence that appears as ~40 nm red-shift of an emission maximum upon cooling from 300 to 77 K. The related PdII/AgI complex, [AgPd(L)2(NO3)3], showing Pd → Ag dative bond of 2.9098(5) Å, has also been synthesized and structurally attested.

Artem'ev A.V. , Rogovoy M.I. , Samsonenko D.G. , Rakhmanova M.I.
Heterobimetallic PtII–AgI complex supported by diphenyl(2-pyrimidyl)phosphine: Synthesis and thermochromic photoluminescence
Inorganic Chemistry Communications. 2020. V.115. 107862 :1-4. DOI: 10.1016/j.inoche.2020.107862 WOS Scopus OpenAlex

Submitted:	Jan 21, 2020
Accepted:	Feb 27, 2020
Published online:	Feb 27, 2020
Published print:	Mar 30, 2020

Web of science:	WOS:000526114400023
Scopus:	2-s2.0-85082447733
OpenAlex:	W3008086026

DB	Citing
OpenAlex	5
Scopus	5
Web of science	4