Heterobimetallic PtII–AgI complex supported by diphenyl(2-pyrimidyl)phosphine: Synthesis and thermochromic photoluminescence Научная публикация
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Inorganic Chemistry Communications
ISSN: 1387-7003 , E-ISSN: 1879-0259 |
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| Вых. Данные | Год: 2020, Том: 115, Номер статьи : 107862, Страниц : 4 DOI: 10.1016/j.inoche.2020.107862 | ||
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Реферат:
The reaction of diphenyl(2-pyrimidyl)phosphine (L) derived complex [Pt(L)2Cl2] with AgNO3 (1:3 M ratio, respectively) results in assembly of heterobimetallic complex [AgPt(L)2(NO3)3], wherein Pt → Ag dative bond of 2.9088(2) Å is formed. This complex features thermochromic photoluminescence that appears as ~40 nm red-shift of an emission maximum upon cooling from 300 to 77 K. The related PdII/AgI complex, [AgPd(L)2(NO3)3], showing Pd → Ag dative bond of 2.9098(5) Å, has also been synthesized and structurally attested.
Библиографическая ссылка:
Artem'ev A.V.
, Rogovoy M.I.
, Samsonenko D.G.
, Rakhmanova M.I.
Heterobimetallic PtII–AgI complex supported by diphenyl(2-pyrimidyl)phosphine: Synthesis and thermochromic photoluminescence
Inorganic Chemistry Communications. 2020. V.115. 107862 :1-4. DOI: 10.1016/j.inoche.2020.107862 WOS Scopus OpenAlex
Heterobimetallic PtII–AgI complex supported by diphenyl(2-pyrimidyl)phosphine: Synthesis and thermochromic photoluminescence
Inorganic Chemistry Communications. 2020. V.115. 107862 :1-4. DOI: 10.1016/j.inoche.2020.107862 WOS Scopus OpenAlex
Даты:
| Поступила в редакцию: | 21 янв. 2020 г. |
| Принята к публикации: | 27 февр. 2020 г. |
| Опубликована online: | 27 февр. 2020 г. |
| Опубликована в печати: | 30 мар. 2020 г. |
Идентификаторы БД:
| Web of science: | WOS:000526114400023 |
| Scopus: | 2-s2.0-85082447733 |
| OpenAlex: | W3008086026 |