SAMAROCENECHALCOGENIDES [{Cp*2Sm(THF)}2(μ-Q)] (Q = S, SE, TE) AS SYNTHETIC EQUIVALENTS OF THE Q2– SYNTHON IN REACTIONS WITH CS2

SAMAROCENECHALCOGENIDES [{Cp*2Sm(THF)}2(μ-Q)] (Q = S, SE, TE) AS SYNTHETIC EQUIVALENTS OF THE Q2– SYNTHON IN REACTIONS WITH CS2 Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2022, Volume: 63, Number: 11, Pages: 1734-1744 Pages count : 11 DOI: 10.1134/S0022476622110026

Authors

Savkov Boris Yurʹevich ¹ , Sukhikh Taisiya Sergeevna ¹ , Konchenko Sergei Nikolaevich ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences

Reactions of decamethylsamarocene monochalcogenides [{Cp*2Sm(THF)}2(μ-Q)] (Cp* = η5-C5(CH3)5; Q = S (1), Se (2), Te (3)) with carbon disulfide are studied. It is established that these reactions lead to the formation of complexes [(Cp*2Sm)2(μ-CS2Q)] (Q = S (4), Se (5), Te (6)), i.e. they can be interpreted as an interaction of Q2– with CS2 in the samarium coordination sphere. The structure of compounds 4-6 was determined by XRD (CCDC CIF files No. 2170732 (4), 2170734 (5), 2170733 (6)). The CS32-bridging ligand in 4 is coordinated to Sm(III) ions by the μ–κ2(S,S′):κ2(S″,S′) type. The heterochalcogenide complexes 5 and 6 are a mixture of isomers with μ–κ2(S,Q):κ2(S′,Q) (main isomer) and μ–κ2(Q,S):κ2(S′,S) types of CS2Q2– coordination (Q = Se, Te).

Savkov B.Y. , Sukhikh T.S. , Konchenko S.N.
SAMAROCENECHALCOGENIDES [{Cp*2Sm(THF)}2(μ-Q)] (Q = S, SE, TE) AS SYNTHETIC EQUIVALENTS OF THE Q2– SYNTHON IN REACTIONS WITH CS2
Journal of Structural Chemistry. 2022. V.63. N11. P.1734-1744. DOI: 10.1134/S0022476622110026 WOS OpenAlex

Савков Б.Ю. , Сухих Т.С. , Конченко С.Н.
Самароценхалькогениды [{Cp*2Sm(THF)}2(μ-Q)] (Q = S, Se, Te) — синтетические эквиваленты синтона Q2– в реакциях с CS2
Журнал структурной химии. 2022. Т.63. №11. С.100561. DOI: 10.26902/JSC_id100561 OpenAlex

Submitted:	Jul 7, 2022
Accepted:	Jul 12, 2022

Web of science:	WOS:000895714200002
OpenAlex:	W4310814013

DB	Citing
OpenAlex	1
Web of science	1