Реферат: Reactions of decamethylsamarocene monochalcogenides [{Cp*2Sm(THF)}2(μ-Q)] (Cp* = η5-C5(CH3)5; Q = S (1), Se (2), Te (3)) with carbon disulfide are studied. It is established that these reactions lead to the formation of complexes [(Cp*2Sm)2(μ-CS2Q)] (Q = S (4), Se (5), Te (6)), i.e. they can be interpreted as an interaction of Q2– with CS2 in the samarium coordination sphere. The structure of compounds 4-6 was determined by XRD (CCDC CIF files No. 2170732 (4), 2170734 (5), 2170733 (6)). The CS32-bridging ligand in 4 is coordinated to Sm(III) ions by the μ–κ2(S,S′):κ2(S″,S′) type. The heterochalcogenide complexes 5 and 6 are a mixture of isomers with μ–κ2(S,Q):κ2(S′,Q) (main isomer) and μ–κ2(Q,S):κ2(S′,S) types of CS2Q2– coordination (Q = Se, Te).

Библиографическая ссылка: Savkov B.Y. , Sukhikh T.S. , Konchenko S.N.
SAMAROCENECHALCOGENIDES [{Cp*2Sm(THF)}2(μ-Q)] (Q = S, SE, TE) AS SYNTHETIC EQUIVALENTS OF THE Q2– SYNTHON IN REACTIONS WITH CS2
Journal of Structural Chemistry. 2022. V.63. N11. P.1734-1744. DOI: 10.1134/S0022476622110026 WOS OpenAlex

Оригинальная: Савков Б.Ю. , Сухих Т.С. , Конченко С.Н.
Самароценхалькогениды [{Cp*2Sm(THF)}2(μ-Q)] (Q = S, Se, Te) — синтетические эквиваленты синтона Q2– в реакциях с CS2
Журнал структурной химии. 2022. Т.63. №11. С.100561. DOI: 10.26902/JSC_id100561 OpenAlex

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Поступила в редакцию:	7 июл. 2022 г.
Принята к публикации:	12 июл. 2022 г.

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Web of science:	WOS:000895714200002
OpenAlex:	W4310814013

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OpenAlex	1
Web of science	1

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