Glycerol as Ligand: The Synthesis, Crystal Structure, and Properties of Compounds [Ln2(H2L)2(H3L)4][Re6Q8(CN)6], Ln = La, Nd, Gd, Q = S, Se

Glycerol as Ligand: The Synthesis, Crystal Structure, and Properties of Compounds [Ln2(H2L)2(H3L)4][Re6Q8(CN)6], Ln = La, Nd, Gd, Q = S, Se Full article

Journal

European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682

Output data

Year: 2006, Volume: 2006, Number: 2, Pages: 298-303 Pages count : 6 DOI: 10.1002/ejic.200500542

Authors

Naumov Nikolai G. ¹ , Tarasenko Maria S. ¹ , Virovets Alexander V. ¹ , Kim Youngmee ² , Kim Sung Jin ² , Fedorov Vladimir E. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, 3, Lavrentieva ave., Novosibirsk 630090, Russia, Fax: +7-3832-309489
2	Department of Chemistry, Ewha Womans University, Seoul 120-750, Korea

The interaction of aqueous solutions of octahedral cluster anions [Re6Q8(CN)6]4– with rare earth cations in the presence of glycerol resulted in the formation of a new family of compounds [Ln2(H2L)2(H3L)4][Re6Q8(CN)6] (where Ln = La, Nd, and Gd; Q = S, Se; H3L = glycerol; H2L– = glycerolate anion). All compounds are isostructural and crystallize in the P space group. Crystal structures are built from octahedral cluster anions [Re6Q8(CN)6]4– and centrosymmetrical dimers [Ln2(H2L)2(H3L)4]4+ that have three different binding modes of glycerol.

Naumov N.G. , Tarasenko M.S. , Virovets A.V. , Kim Y. , Kim S.J. , Fedorov V.E.
Glycerol as Ligand: The Synthesis, Crystal Structure, and Properties of Compounds [Ln2(H2L)2(H3L)4][Re6Q8(CN)6], Ln = La, Nd, Gd, Q = S, Se
European Journal of Inorganic Chemistry. 2006. V.2006. N2. P.298-303. DOI: 10.1002/ejic.200500542 WOS Scopus OpenAlex

Submitted:	Jun 22, 2005
Accepted:	Dec 5, 2005
Published online:	Dec 5, 2005
Published print:	Jan 31, 2006

Web of science:	WOS:000235349100004
Scopus:	2-s2.0-31644438114
OpenAlex:	W2057234704

DB	Citing
OpenAlex	28
Scopus	30
Web of science	28