Framework polymers based on octahedral chalcocyanide cluster [Re6Q8(CN)6]4−/3− anions (Q = Se, Te) and [Nd(Bipy)n]3+ Complexes (n = 1, 2) Full article
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Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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| Output data | Year: 2006, Volume: 32, Number: 7, Pages: 494-503 Pages count : 10 DOI: 10.1134/s1070328406070062 | ||
| Tags | Coordination Chemistry, Coordination Polymer, Bipy, Cyano Group, Cluster Anion | ||
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Abstract:
Interaction of salts of the cluster anions {Re [Re6Q8(CN)6]4−/3− (Q = Se, Te) with Nd salts in the presence of 2,2′-bipyridyl (Bipy) ligand brings about new coordination polymers: Pr(n)4N[{Nd(Bipy)(H2O)4} {Re6Se8(CN)6}] · 2H2O (I) (space group C2/c, a = 18.2918(16) Å, b = 14.9972(13) Å, c = 37.513(3) Å, β = 102.046(4)°, V = 10064.2(15) Å3, Z = 8), [{Nd(Bipy)2(H2O)} {Re6Se8(CN)6}] (II) (space group C2/c, a = 15.8668(3) Å, b = 13.5403(3) Å, c = 20.5189(4) Å, β = 110.135(1)°, V = 4138.89(15) Å3, Z = 4), and [{Nd(Bipy)(EtOH)(H2O)4}{Re6Te8(CN)6}] · EtOH (III) (space group
, a = 9.4733(6) Å, b = 12.5326(8) Å, c = 17.2374(11) Å, α = 96.561(2)°, β = 90.310(2)°, γ = 94.876(2)°, V = 4138.89(15) Å3, Z = 4). The compounds synthesized are characterized by single-crystal X-ray diffraction and IR methods. Compounds I and III have layered (2D) structures, compound II is a framework (3D) polymer.
Cite:
Tarasenko M.S.
, Naumov N.G.
, Naumov D.Y.
, Kuratieva N.V.
, Fedorov V.E.
Framework polymers based on octahedral chalcocyanide cluster [Re6Q8(CN)6]4−/3− anions (Q = Se, Te) and [Nd(Bipy)n]3+ Complexes (n = 1, 2)
Russian Journal of Coordination Chemistry. 2006. V.32. N7. P.494-503. DOI: 10.1134/s1070328406070062 WOS Scopus OpenAlex
Framework polymers based on octahedral chalcocyanide cluster [Re6Q8(CN)6]4−/3− anions (Q = Se, Te) and [Nd(Bipy)n]3+ Complexes (n = 1, 2)
Russian Journal of Coordination Chemistry. 2006. V.32. N7. P.494-503. DOI: 10.1134/s1070328406070062 WOS Scopus OpenAlex
Dates:
| Submitted: | Sep 5, 2005 |
| Accepted: | Sep 5, 2005 |
| Published print: | Jul 1, 2006 |
| Published online: | Jul 1, 2006 |
Identifiers:
| Web of science: | WOS:000239375400006 |
| Scopus: | 2-s2.0-33746218743 |
| OpenAlex: | W2059081647 |