Sciact
  • EN
  • RU

A series of three-dimensional coordination polymers with general formula [{Ln(H2O)n}{Re6Te8(CN)6}]·xH2O (Ln=Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb; n=3, 4, x=0, 2.5) Научная публикация

Журнал Polyhedron
ISSN: 1873-3719 , E-ISSN: 0277-5387
Вых. Данные Год: 2008, Том: 27, Номер: 11, Страницы: 2357-2364 Страниц : 9 DOI: 10.1016/j.poly.2008.04.054
Ключевые слова Rhenium, Octahedral cluster, Cyanide, Lanthanides, Coordination framework
Авторы Tarasenko Maria S. 1 , Naumov Nikolay G. 2 , Naumov Dmitry Yu. 1 , Kim Sung Jin 2 , Fedorov Vladimir E. 1
Организации
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3 Ak. Lavrentiev Ave., Novosibirsk 630090, Russia
2 Department of Chemistry and Nano Sciences, Ewha Womans University, Seoul 120-750, Republic of Korea

Реферат: A series of new compounds containing rare earth cations (Eu to Yb) and paramagnetic cluster anion [Re6Te8(CN)6]3− was prepared and investigated. The X-ray structural analyses have revealed that the compounds [{Ln(H2O)4}{Re6Te8(CN)6}]·2.5H2O; Ln=Eu (1), Tb (3), Dy (4), Ho (5), Er (6), Tm (7), [{Gd(H2O)3}{Re6Te8(CN)6}]·2.5H2O (2) and [{Yb(H2O)4}{Re6Te8(CN)6}] (8) are three-dimensional polymers based on Re–CN–Ln interactions. Measurements of magnetic susceptibility for 2 and 5 showed that effective magnetic moment (at 300K) was 8.13μB for compound 2 and 10.79μB for compound 5 with weak antiferromagnetic ordering appeared at low temperatures.
Библиографическая ссылка: Tarasenko M.S. , Naumov N.G. , Naumov D.Y. , Kim S.J. , Fedorov V.E.
A series of three-dimensional coordination polymers with general formula [{Ln(H2O)n}{Re6Te8(CN)6}]·xH2O (Ln=Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb; n=3, 4, x=0, 2.5)
Polyhedron. 2008. V.27. N11. P.2357-2364. DOI: 10.1016/j.poly.2008.04.054 WOS Scopus OpenAlex
Даты:
Поступила в редакцию: 18 дек. 2007 г.
Принята к публикации: 29 апр. 2008 г.
Опубликована online: 4 июл. 2008 г.
Опубликована в печати: 4 авг. 2008 г.
Идентификаторы БД:
Web of science: WOS:000258435700017
Scopus: 2-s2.0-47049131600
OpenAlex: W2072272945
Цитирование в БД:
БД Цитирований
OpenAlex 32
Scopus 31
Web of science 28
Альметрики:
32
CITATIONS
32 total citations on Dimensions.
32 Total citations
3 Recent citations
4.4 Field Citation Ratio
n/a Relative Citation Ratio