Crystal structure of Cs[Gd(H2O)4Re6Te8(CN)6]·4H2O

Crystal structure of Cs[Gd(H2O)4Re6Te8(CN)6]·4H2O Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2008, Volume: 49, Number: 6, Pages: 1128-1131 Pages count : 4 DOI: 10.1007/s10947-008-0191-4

Tags

rhenium, octahedral cluster, cyanide complex, gadolinium, crystal structure

Authors

Tarasenko M.S. ¹ , Naumov N.G. ^1,2 , Virovets A.V. ¹ , Kim S.J. ² , Fedorov V.E. ¹

Affiliations

1	A. V. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Division, Novosibirsk, Russia
2	Ewha Womans University, Seoul, Korea

The structure of the salt Cs[Gd(H2O)4Re6Te8(CN)6]·4H2O (space group P-1, a = 9.436(5) Å, b = 12.365(7) Å, c = 15.187(8)Å, α = 89.104(10)°, β = 86.996(10)°, γ = 82.304(9)°) has been established by single crystal XRD. The structure of the compound features layers involving Gd3+ cations bound to cluster anions [Re6Te8(CN)6]4− through cyanide groups. The interlayer space contains cesium cations and crystallization water molecules.

Tarasenko M.S. , Naumov N.G. , Virovets A.V. , Kim S.J. , Fedorov V.E.
Crystal structure of Cs[Gd(H2O)4Re6Te8(CN)6]·4H2O
Journal of Structural Chemistry. 2008. V.49. N6. P.1128-1131. DOI: 10.1007/s10947-008-0191-4 WOS Scopus OpenAlex

Submitted:	Jan 31, 2008
Accepted:	Apr 30, 2008
Published print:	Nov 30, 2008
Published online:	Feb 4, 2009

Web of science:	WOS:000263080500024
Scopus:	2-s2.0-59549095197
OpenAlex:	W1975116995

DB	Citing
OpenAlex	6
Scopus	6
Web of science	5