H–D exchange in metal carbene complexes: Structure of cluster (μ-H)(μ-OCD3)Os3(CO)9{:C(CD3)NC2H8O} Full article
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Journal of Molecular Structure
ISSN: 0022-2860 , E-ISSN: 1872-8014 |
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| Output data | Year: 2015, Volume: 1097, Pages: 157-160 Pages count : 4 DOI: 10.1016/j.molstruc.2015.05.026 | ||||
| Tags | Osmium clustersCluster carbenesFisher type carbenesCH-acidityLigand substitution | ||||
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Abstract:
X-ray and spectroscopic data for the new complex (μ-H)(μ-OCH3)Os3(CO)9{:C(CD3)NC2H8O} (2) obtained in the reaction of the (μ-H)(μ-Cl)Os3(CO)9{:C(CH3)NC2H8O} (1) with NaOCD3 in CD3OD solution are reported. It is shown that cluster 1 has the property of CH-acidity inherent of Fisher type carbenes. This had demonstrated using hydrogen deuterium exchange reaction in the presence of a strong base. Bridging chlorine to metoxide ligand substitution takes place during the reaction. The molecular structure of 2 is compared with known analogues.
Cite:
Savkov B.
, Maksakov V.
, Kuratieva N.
H–D exchange in metal carbene complexes: Structure of cluster (μ-H)(μ-OCD3)Os3(CO)9{:C(CD3)NC2H8O}
Journal of Molecular Structure. 2015. V.1097. P.157-160. DOI: 10.1016/j.molstruc.2015.05.026 WOS Scopus РИНЦ OpenAlex
H–D exchange in metal carbene complexes: Structure of cluster (μ-H)(μ-OCD3)Os3(CO)9{:C(CD3)NC2H8O}
Journal of Molecular Structure. 2015. V.1097. P.157-160. DOI: 10.1016/j.molstruc.2015.05.026 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Mar 4, 2015 |
| Accepted: | May 11, 2015 |
| Published print: | May 19, 2015 |
| Published online: | May 19, 2015 |
Identifiers:
| Web of science: | WOS:000358555700022 |
| Scopus: | 2-s2.0-84930681145 |
| Elibrary: | 24046195 |
| OpenAlex: | W232770341 |