SYNTHESIS AND STRUCTURE OF A NEW NEODYMIUM COMPLEX WITH AN UNUSUAL TYPE OF COORDINATION OF THE BENZYL LIGAND Full article
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Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Output data | Year: 2021, Volume: 62, Number: 1, Pages: 116-122 Pages count : 7 DOI: 10.1134/s0022476621010145 | ||||
| Tags | coordination compounds, lanthanides, neodymium, benzyl complexes, crystal structure. | ||||
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Abstract:
A reaction of [Cp'''2NdI](1) (Cp′′′ = 1,3,4-tris(tert-butyl)cyclopentadienide) with BzK (Bz = C6H5CH2) in toluene is studied. The result of this reaction was expected to be Bz–substitution for I–, however, it is found that the main reaction product is a new binuclear neodymium complex [(Cp′′′BzNd)2O] (2), containing a bridging oxygen atom. Structures of (1) and (2) are determined by single crystal X-ray diffraction analysis.
Cite:
Demkin A.G.
, Savkov B.Y.
, Sukhikh T.S.
, Konchenko S.N.
SYNTHESIS AND STRUCTURE OF A NEW NEODYMIUM COMPLEX WITH AN UNUSUAL TYPE OF COORDINATION OF THE BENZYL LIGAND
Journal of Structural Chemistry. 2021. V.62. N1. P.116-122. DOI: 10.1134/s0022476621010145 WOS Scopus РИНЦ OpenAlex
SYNTHESIS AND STRUCTURE OF A NEW NEODYMIUM COMPLEX WITH AN UNUSUAL TYPE OF COORDINATION OF THE BENZYL LIGAND
Journal of Structural Chemistry. 2021. V.62. N1. P.116-122. DOI: 10.1134/s0022476621010145 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Jun 22, 2020 |
| Accepted: | Jul 24, 2020 |
| Published online: | Feb 15, 2021 |
Identifiers:
| Web of science: | WOS:000618238700014 |
| Scopus: | 2-s2.0-85100919907 |
| Elibrary: | 46753276 |
| OpenAlex: | W3132412155 |