SYNTHESIS AND STRUCTURE OF A NEW NEODYMIUM COMPLEX WITH AN UNUSUAL TYPE OF COORDINATION OF THE BENZYL LIGAND

SYNTHESIS AND STRUCTURE OF A NEW NEODYMIUM COMPLEX WITH AN UNUSUAL TYPE OF COORDINATION OF THE BENZYL LIGAND Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2021, Volume: 62, Number: 1, Pages: 116-122 Pages count : 7 DOI: 10.1134/s0022476621010145

Tags

coordination compounds, lanthanides, neodymium, benzyl complexes, crystal structure.

Authors

Demkin A.G. ^1,2 , Savkov B.Yu. ¹ , Sukhikh T.S. ¹ , Konchenko S.N. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences
2	Novosibirsk State University

A reaction of [Cp'''2NdI](1) (Cp′′′ = 1,3,4-tris(tert-butyl)cyclopentadienide) with BzK (Bz = C6H5CH2) in toluene is studied. The result of this reaction was expected to be Bz–substitution for I–, however, it is found that the main reaction product is a new binuclear neodymium complex [(Cp′′′BzNd)2O] (2), containing a bridging oxygen atom. Structures of (1) and (2) are determined by single crystal X-ray diffraction analysis.

Demkin A.G. , Savkov B.Y. , Sukhikh T.S. , Konchenko S.N.
SYNTHESIS AND STRUCTURE OF A NEW NEODYMIUM COMPLEX WITH AN UNUSUAL TYPE OF COORDINATION OF THE BENZYL LIGAND
Journal of Structural Chemistry. 2021. V.62. N1. P.116-122. DOI: 10.1134/s0022476621010145 WOS Scopus РИНЦ OpenAlex

Submitted:	Jun 22, 2020
Accepted:	Jul 24, 2020
Published online:	Feb 15, 2021

Web of science:	WOS:000618238700014
Scopus:	2-s2.0-85100919907
Elibrary:	46753276
OpenAlex:	W3132412155

DB	Citing
Web of science	3
Scopus	4
Elibrary	7
OpenAlex	4