FIRST EXAMPLES OF MOLECULAR POLYCHALCOGENIDE COMPLEXES OF THULIUM Full article
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Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Output data | Year: 2021, Volume: 62, Number: 6, Pages: 957-965 Pages count : 9 DOI: 10.1134/s0022476621060159 | ||
| Tags | coordination compounds, lanthanides, thulium, chalcogenide complexes, crystal structure | ||
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Abstract:
Two new polychalcogenide complexes of thulium are obtained by the interaction of [Cp′′′2Tm] (Cp′′′ = 1,3,4-tris(tert-butyl)cyclopentadienide) (1) with elemental sulfur under different conditions:[(Cp′′′2Tm)2S2] (2) and [K(18-cr-6)][Cp′′′2TmS2](18-cr-6 – 1,4,7,10,13,16-hexaoxa cyclooctadecane) (3). A reaction of complex 2 with CS2 in toluene is studied. It results in[(Cp′′′2Tm)2CS4] compound (4) that is the first example of Tm(III) perthiocarbonate complex. Structures of 2-4 are determined by single crystal X-ray diffraction.
Cite:
Demkin A.G.
, Savkov B.Y.
, Sukhikh T.S.
, Konchenko S.N.
FIRST EXAMPLES OF MOLECULAR POLYCHALCOGENIDE COMPLEXES OF THULIUM
Journal of Structural Chemistry. 2021. V.62. N6. P.957-965. DOI: 10.1134/s0022476621060159 WOS Scopus РИНЦ OpenAlex
FIRST EXAMPLES OF MOLECULAR POLYCHALCOGENIDE COMPLEXES OF THULIUM
Journal of Structural Chemistry. 2021. V.62. N6. P.957-965. DOI: 10.1134/s0022476621060159 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Dec 8, 2020 |
| Accepted: | Dec 11, 2020 |
| Published online: | Jun 25, 2021 |
Identifiers:
| Web of science: | WOS:000667904000015 |
| Scopus: | 2-s2.0-85111077788 |
| Elibrary: | 46935381 |
| OpenAlex: | W3176230303 |