Chiral coordination polymers based on Re cluster complexes, Cu2+ cations, and 1,2S,3S,4-tetraaminobutane Full article
Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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Output data | Year: 2005, Volume: 31, Number: 4, Pages: 269-281 Pages count : 13 DOI: 10.1007/s11173-005-0088-0 | ||||||
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Abstract:
Reactions of octahedral and tetrahedral chalcocyanide cluster complexes of Re with Cu2+ cations and 1,2S,3S,4-tetraaminobutane (Threo-tab) were used to synthesize and study the structures of the following six novel chiral complexes: [{Cu2(NH3)(Threo-tab)3}Re6S8(CN)6] ⋅ 3H2O (I) (where Threo is 1,2S,3S,4-tetraaminobutane), [{Cu2(NH3)(Threo-tab)3}Re6Se8(CN)6] ⋅ 2H2O (II), [{Cu(Threo-tab)}2Re6Te8(CN)6] ⋅ 13.5H2O (III), [{Cu(Threo-tab)}2Re4Te4(CN)12] ⋅ 6.5H2O (IV), [{Cu2(NH3)(Threo-tab)2}Re4Te4(CN)12] ⋅ 4H2O (V), and [{Cu(NH3)(Threo-tab)}]2[Re4S3.4Te0.6(CN)12] ⋅ 1.25H2O (VI). The structures of complexes I–IV contain extended channels of sufficiently large size capable of including “guest” molecules
Cite:
Mironov Y.V.
, Naumov N.G.
, Brylev K.A.
, Efremova O.A.
, Fedorov V.E.
, Hegetschweiler K.
Chiral coordination polymers based on Re cluster complexes, Cu2+ cations, and 1,2S,3S,4-tetraaminobutane
Russian Journal of Coordination Chemistry. 2005. V.31. N4. P.269-281. DOI: 10.1007/s11173-005-0088-0 WOS Scopus РИНЦ OpenAlex
Chiral coordination polymers based on Re cluster complexes, Cu2+ cations, and 1,2S,3S,4-tetraaminobutane
Russian Journal of Coordination Chemistry. 2005. V.31. N4. P.269-281. DOI: 10.1007/s11173-005-0088-0 WOS Scopus РИНЦ OpenAlex
Original:
Миронов Ю.В.
, Наумов Н.Г.
, Брылев К.А.
, Ефремова О.А.
, Федоров В.Е.
, Хегечвайлер К.
Хиральные координационные полимеры на основе кластерных комплексов рения, катионов Cu2+ и 1,2S,3S,4-тетрааминобутана
Координационная химия. 2005. Т.31. №4. С.289-301.
Хиральные координационные полимеры на основе кластерных комплексов рения, катионов Cu2+ и 1,2S,3S,4-тетрааминобутана
Координационная химия. 2005. Т.31. №4. С.289-301.
Dates:
Submitted: | Jul 12, 2004 |
Published online: | Apr 1, 2005 |
Identifiers:
Web of science: | WOS:000228780100008 |
Scopus: | 2-s2.0-18144417854 |
Elibrary: | 13482618 |
OpenAlex: | W1974399153 |