Sciact
  • EN
  • RU

Chiral coordination polymers based on Re cluster complexes, Cu2+ cations, and 1,2S,3S,4-tetraaminobutane Full article

Journal Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318
Output data Year: 2005, Volume: 31, Number: 4, Pages: 269-281 Pages count : 13 DOI: 10.1007/s11173-005-0088-0
Authors Mironov Yu.V. 1 , Naumov N.G. 2 , Brylev K.A. 1 , Efremova O.A. 2 , Fedorov V.E. 2 , Hegetschweiler K. 3
Affiliations
1 Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences
2 Novosibirsk State University
3 Universitaet des Saarlandes Anorganische Chemie

Abstract: Reactions of octahedral and tetrahedral chalcocyanide cluster complexes of Re with Cu2+ cations and 1,2S,3S,4-tetraaminobutane (Threo-tab) were used to synthesize and study the structures of the following six novel chiral complexes: [{Cu2(NH3)(Threo-tab)3}Re6S8(CN)6] ⋅ 3H2O (I) (where Threo is 1,2S,3S,4-tetraaminobutane), [{Cu2(NH3)(Threo-tab)3}Re6Se8(CN)6] ⋅ 2H2O (II), [{Cu(Threo-tab)}2Re6Te8(CN)6] ⋅ 13.5H2O (III), [{Cu(Threo-tab)}2Re4Te4(CN)12] ⋅ 6.5H2O (IV), [{Cu2(NH3)(Threo-tab)2}Re4Te4(CN)12] ⋅ 4H2O (V), and [{Cu(NH3)(Threo-tab)}]2[Re4S3.4Te0.6(CN)12] ⋅ 1.25H2O (VI). The structures of complexes I–IV contain extended channels of sufficiently large size capable of including “guest” molecules
Cite: Mironov Y.V. , Naumov N.G. , Brylev K.A. , Efremova O.A. , Fedorov V.E. , Hegetschweiler K.
Chiral coordination polymers based on Re cluster complexes, Cu2+ cations, and 1,2S,3S,4-tetraaminobutane
Russian Journal of Coordination Chemistry. 2005. V.31. N4. P.269-281. DOI: 10.1007/s11173-005-0088-0 WOS Scopus РИНЦ OpenAlex
Original: Миронов Ю.В. , Наумов Н.Г. , Брылев К.А. , Ефремова О.А. , Федоров В.Е. , Хегечвайлер К.
Хиральные координационные полимеры на основе кластерных комплексов рения, катионов Cu2+ и 1,2S,3S,4-тетрааминобутана
Координационная химия. 2005. Т.31. №4. С.289-301.
Dates:
Submitted: Jul 12, 2004
Published online: Apr 1, 2005
Identifiers:
Web of science: WOS:000228780100008
Scopus: 2-s2.0-18144417854
Elibrary: 13482618
OpenAlex: W1974399153
Citing:
DB Citing
OpenAlex 15
Web of science 14
Scopus 12
Elibrary 12
Altmetrics: