SYNTHESIS AND CRYSTAL STRUCTURE OF LiTb6O5(BO3)3 | Sciact - научная деятельность

SYNTHESIS AND CRYSTAL STRUCTURE OF LiTb6O5(BO3)3 Научная публикация

Журнал

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Вых. Данные

Год: 2021, Том: 62, Номер: 2, Страницы: 230-235 Страниц : 6 DOI: 10.1134/s0022476621020062

Ключевые слова

terbium, borate, solid state synthesis, crystal structure

Авторы

Nikolaev R.E. ¹ , Tarasenko M.S. ¹ , Kuratieva N.V. ¹ , Trifonov V.A. ¹ , Naumov N.G. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Single crystals of compound LiTb6O5(BO3)3 suitable for X-ray diffraction are prepared by the flux growth method. The compound crystallizes in the P21/n space group, a = 8.4350 Å, b = 15.6232 Å, c = 8.9025 Å, β = 92.041°. The obtained compound belongs to the class of 3D-framework oxoborates. It has a similar structure to that of known LiGd6O5(BO3)3 but is not isostructural to the latter. Both structures are derivatives of fluorite, the predecessor compound in this structural series. The cationic part of the predecessor′s structural type is filled by Tb3+ and Li+ cations, while its anionic part is formed by oxide ions and oxygen atoms of borate anions. The melting point (1375±15 °C) and the band gap (4 eV) are determined for LiTb6O5(BO3)3.

Nikolaev R.E. , Tarasenko M.S. , Kuratieva N.V. , Trifonov V.A. , Naumov N.G.
SYNTHESIS AND CRYSTAL STRUCTURE OF LiTb6O5(BO3)3
Journal of Structural Chemistry. 2021. V.62. N2. P.230-235. DOI: 10.1134/s0022476621020062 WOS Scopus РИНЦ OpenAlex

Поступила в редакцию:	17 июл. 2020 г.
Принята к публикации:	10 авг. 2020 г.
Опубликована в печати:	16 мар. 2021 г.
Опубликована online:	16 мар. 2021 г.

Web of science:	WOS:000629622600006
Scopus:	2-s2.0-85102705182
РИНЦ:	46756888
OpenAlex:	W3137800034

БД	Цитирований
OpenAlex	2
Web of science	2
Scopus	2
РИНЦ	3