Facile synthesis of triple Ni-Mo-W alloys and their catalytic properties in chemical vapor deposition of chlorinated hydrocarbons

Facile synthesis of triple Ni-Mo-W alloys and their catalytic properties in chemical vapor deposition of chlorinated hydrocarbons Full article

Journal

Journal of Alloys and Compounds
ISSN: 0925-8388 , E-ISSN: 1873-4669

Output data

Year: 2021, Volume: 866, Article number : 158778, Pages count : 12 DOI: 10.1016/j.jallcom.2021.158778

Tags

Nickel alloys, X-ray diffraction analysis, 1,2-Dichloroethane, CCVD, Carbon nanofibers

Authors

Shubin Yury V. ^1,2 , Bauman Yury I. ³ , Plyusnin Pavel E. ¹ , Mishakov Ilya V. ^2,3 , Tarasenko Maria S. ¹ , Mel'gunov Maxim S. ^2,3 , Stoyanovskii Vladimir O. ³ , Vedyagin Aleksey A. ³

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russian Federation
2	National Research Novosibirsk State University, Novosibirsk, Russian Federation
3	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russian Federation

Highlights •The catalytic chemical vapor deposition process of 1,2-dichloroethane was studied. •The sponge-like porous Ni-Mo-W alloys were prepared via reductive thermolysis. •The simultaneous presence of Mo and W was shown to have a synergetic effect. •The resulting carbon deposits were the fibers of a segmented structure. Abstract The utilization of chlorine-containing organic wastes remains an actual problem. In the present research, sponge-like porous Ni-Mo-W alloys were prepared and used as catalysts for the catalytic chemical vapor deposition of 1,2-dichloroethane. The synthesis of the alloys was performed via a facile approach of high-temperature reductive thermolysis of the preliminarily prepared multicomponent precursors. The formation of alloys of exact composition was proven by precise X-ray diffraction analysis. The catalytic activity of the alloys in the decomposition of 1,2-dichloroethane was studied in a flow-through reactor at 600 °C for 2 h. The simultaneous presence of Mo and W in the composition of the Ni-based alloys was shown to have a synergetic effect on the process efficiency. The diameter of these fibers was found to be comparable with the size of metal particles formed as a result of initial alloys self-disintegration under the action of the aggressive reaction medium.

Shubin Y.V. , Bauman Y.I. , Plyusnin P.E. , Mishakov I.V. , Tarasenko M.S. , Mel'gunov M.S. , Stoyanovskii V.O. , Vedyagin A.A.
Facile synthesis of triple Ni-Mo-W alloys and their catalytic properties in chemical vapor deposition of chlorinated hydrocarbons
Journal of Alloys and Compounds. 2021. V.866. 158778 :1-12. DOI: 10.1016/j.jallcom.2021.158778 WOS Scopus РИНЦ OpenAlex

Submitted:	Nov 11, 2020
Accepted:	Jan 15, 2021
Published online:	Feb 1, 2021
Published print:	Feb 5, 2021

Web of science:	WOS:000630241800017
Scopus:	2-s2.0-85100372691
Elibrary:	44959014
OpenAlex:	W3126267017

DB	Citing
OpenAlex	14
Web of science	12
Scopus	14
Elibrary	11