Rearrangement of {Mo6S8} cluster unit to {Mo4S4} and new {Mo6S6} clusters: structure of salts K6[Mo4S4(CN)12]·10H2O and (18-crown-6K)8[Mo6S6(CN)16]·17.5H2O Full article
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Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Output data | Year: 2003, Volume: 44, Number: 4, Pages: 698-703 Pages count : 6 DOI: 10.1023/b:jory.0000017948.93775.91 | ||||
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Abstract:
Two new compounds containing molybdenum thiocyanide cluster anions, K6[Mo4S4(CN)12]·10H2O (1) and (18-crown-6K)8[Mo6S6(CN)16]·17.5H2O (2), were synthesized and investigated by X-ray structure analysis. Crystal data: a=11.8430(17), b=11.8430(17), c=35.170(7) Å, V=4932.8(14) Å3, space group I41/a, Z=4, dcalc=1.563 g/cm3 for 1; a=28.7513(5), b=18.4190(3), c=20.7586(4) Å, β=118.5982(7)°, V=9651.9(3) Å3, space group C2/m, Z=4, dcalc =1.563 g/cm3 for 2. The [Mo4S4(CN)12]6- cluster anion in 1 has an ordinary structure typical of cubane transition metal complexes. In the structure of the [Mo6S6(CN)16]8- anion of 2, two crystallographically independent molybdenum atoms form a Mo6 metallocluster, represented as two edge-sharing tetrahedra.
Cite:
Naumov N.G.
, Brylev K.A.
, Cordier S.
, Hernandez O.
, Perrin C.
, Fedorov V.E.
Rearrangement of {Mo6S8} cluster unit to {Mo4S4} and new {Mo6S6} clusters: structure of salts K6[Mo4S4(CN)12]·10H2O and (18-crown-6K)8[Mo6S6(CN)16]·17.5H2O
Journal of Structural Chemistry. 2003. V.44. N4. P.698-703. DOI: 10.1023/b:jory.0000017948.93775.91 WOS Scopus РИНЦ OpenAlex
Rearrangement of {Mo6S8} cluster unit to {Mo4S4} and new {Mo6S6} clusters: structure of salts K6[Mo4S4(CN)12]·10H2O and (18-crown-6K)8[Mo6S6(CN)16]·17.5H2O
Journal of Structural Chemistry. 2003. V.44. N4. P.698-703. DOI: 10.1023/b:jory.0000017948.93775.91 WOS Scopus РИНЦ OpenAlex
Original:
Наумов Н.Г.
, Брылев К.А.
, Кордиер С.
, Хернандез О.
, Перрин К.
, Федоров В.Е.
Перегруппировка кластерного фрагмента {Mo6S8} до {Mo4S4} и нового кластерного ядра {Mo6S6}: структура солей K6[Mo4S4(CN)12]*10H2O и (18-crown-6K)8[Mo6S6(CN)16]*17.5H2O
Журнал структурной химии. 2003. Т.44. №4. С.760-765.
Перегруппировка кластерного фрагмента {Mo6S8} до {Mo4S4} и нового кластерного ядра {Mo6S6}: структура солей K6[Mo4S4(CN)12]*10H2O и (18-crown-6K)8[Mo6S6(CN)16]*17.5H2O
Журнал структурной химии. 2003. Т.44. №4. С.760-765.
Dates:
| Submitted: | May 31, 2002 |
| Published online: | Jul 1, 2003 |
Identifiers:
| Web of science: | WOS:000220939800022 |
| Scopus: | 2-s2.0-1342330522 |
| Elibrary: | 13424553 |
| OpenAlex: | W307892872 |