Novel inorganic ionic compounds based on Re6 chalcocyanide cluster complexes: synthesis and crystal structures of [CuNH3(trien)]2[Re6S8(CN)6]·7H2O, [CuNH3(trien)]2[Re6Se8(CN)6] and [CuNH3(trien)]2[Re6Te8(CN)6]·H2O

Novel inorganic ionic compounds based on Re6 chalcocyanide cluster complexes: synthesis and crystal structures of [CuNH3(trien)]2[Re6S8(CN)6]·7H2O, [CuNH3(trien)]2[Re6Se8(CN)6] and [CuNH3(trien)]2[Re6Te8(CN)6]·H2O Full article

Journal

Polyhedron
ISSN: 1873-3719 , E-ISSN: 0277-5387

Output data

Year: 2003, Volume: 22, Number: 25, Pages: 3383-3387 Pages count : 5 DOI: 10.1016/j.poly.2003.08.015

Authors

Brylev Konstantin A ¹ , Naumov Nikolai G ¹ , Peris Gabriel ² , Llusar Rosa ³ , Fedorov Vladimir E ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry of Russian Academy of Sciences
2	Servei Central d’Instrumentació Cientı́fica, Campus Riu Sec, Universitat Jaume I
3	Departament de Ciencies Experimentals, Campus Riu Sec, Universitat Jaume I

Three new octahedral rhenium chalcocyanide cluster compounds [CuNH3(trien)]2[Re6S8(CN)6]·7H2O (1), [CuNH3(trien)]2[Re6Se8(CN)6] (2) and [CuNH3(trien)]2[Re6Te8(CN)6]·H2O (3) exhibiting ionic structures have been obtained by the diffusion of an ammonia solution of KCs3[Re6S8(CN)6] (for 1), K4[Re6Se8(CN)6]·3.5H2O (for 2) or Cs4[Re6Te8(CN)6]·2H2O (for 3) into a glycerol solution of CuCl2·2H2O in the presence of trien (trien=triethylenetetramine). The compounds have been characterized by single-crystal X-ray diffraction. All three compounds contain a cationic complex [CuNH3(trien)]2+ which was not described previously.

Brylev K.A. , Naumov N.G. , Peris G. , Llusar R. , Fedorov V.E.
Novel inorganic ionic compounds based on Re6 chalcocyanide cluster complexes: synthesis and crystal structures of [CuNH3(trien)]2[Re6S8(CN)6]·7H2O, [CuNH3(trien)]2[Re6Se8(CN)6] and [CuNH3(trien)]2[Re6Te8(CN)6]·H2O
Polyhedron. 2003. V.22. N25. P.3383-3387. DOI: 10.1016/j.poly.2003.08.015 WOS Scopus РИНЦ OpenAlex

Submitted:	May 3, 2003
Published online:	Oct 16, 2003

Web of science:	WOS:000186549700018
Scopus:	2-s2.0-0842309281
Elibrary:	13435937
OpenAlex:	W1973294633

DB	Citing
Web of science	24
Scopus	25
Elibrary	25
OpenAlex	26